Effect of Tb-doped Concentration Variation on the Electrical and Dielectric Properties of CaF₂ Nanoparticles

Nanomaterials
Xiaoyan CuiChunxiao Gao

Abstract

Calcium fluoride (CaF₂) nanoparticles with various terbium (Tb) doping concentrations were investigated by X-ray diffraction (XRD), transmission electron microscopy (TEM), and alternating current (AC) impedance measurement. The original shape and structure of CaF₂ nanoparticles were retained after doping. In all the samples, the dominant charge carriers were electrons, and the F- ion transference number increased with increasing Tb concentration. The defects in the grain region considerably contributed to the electron transportation process. When the Tb concentration was less than 3%, the effect of the ionic radius variation dominated and led to the diffusion of the F- ions and facilitated electron transportation. When the Tb concentration was greater than 3%, the increasing deformation potential scattering dominated, impeding F- ion diffusion and electron transportation. The substitution of Ca2+ by Tb3+ enables the electron and ion hopping in CaF₂ nanocrystals, resulting in increased permittivity.

References

Jun 10, 2003·Journal of Radiation Research·Yasunori Fukuda
Sep 11, 2004·Optics Letters·A LuccaR Moncorgé
Jun 1, 2006·Journal of the American Chemical Society·Min ChenShouheng Sun
Aug 15, 1997·Optics Letters·D B BarberC K Ober
Sep 25, 2009·Journal of the American Chemical Society·Guofeng WangYadong Li

❮ Previous
Next ❯

Citations

Dec 6, 2018·Nanomaterials·Xiaoyan CuiChunxiao Gao

❮ Previous
Next ❯

Methods Mentioned

BETA
X-ray
transmission electron microscopy

Related Concepts

Trending Feeds

COVID-19

Coronaviruses encompass a large family of viruses that cause the common cold as well as more serious diseases, such as the ongoing outbreak of coronavirus disease 2019 (COVID-19; formally known as 2019-nCoV). Coronaviruses can spread from animals to humans; symptoms include fever, cough, shortness of breath, and breathing difficulties; in more severe cases, infection can lead to death. This feed covers recent research on COVID-19.

Blastomycosis

Blastomycosis fungal infections spread through inhaling Blastomyces dermatitidis spores. Discover the latest research on blastomycosis fungal infections here.

Nuclear Pore Complex in ALS/FTD

Alterations in nucleocytoplasmic transport, controlled by the nuclear pore complex, may be involved in the pathomechanism underlying multiple neurodegenerative diseases including Amyotrophic Lateral Sclerosis and Frontotemporal Dementia. Here is the latest research on the nuclear pore complex in ALS and FTD.

Applications of Molecular Barcoding

The concept of molecular barcoding is that each original DNA or RNA molecule is attached to a unique sequence barcode. Sequence reads having different barcodes represent different original molecules, while sequence reads having the same barcode are results of PCR duplication from one original molecule. Discover the latest research on molecular barcoding here.

Chronic Fatigue Syndrome

Chronic fatigue syndrome is a disease characterized by unexplained disabling fatigue; the pathology of which is incompletely understood. Discover the latest research on chronic fatigue syndrome here.

Evolution of Pluripotency

Pluripotency refers to the ability of a cell to develop into three primary germ cell layers of the embryo. This feed focuses on the mechanisms that underlie the evolution of pluripotency. Here is the latest research.

Position Effect Variegation

Position Effect Variagation occurs when a gene is inactivated due to its positioning near heterochromatic regions within a chromosome. Discover the latest research on Position Effect Variagation here.

STING Receptor Agonists

Stimulator of IFN genes (STING) are a group of transmembrane proteins that are involved in the induction of type I interferon that is important in the innate immune response. The stimulation of STING has been an active area of research in the treatment of cancer and infectious diseases. Here is the latest research on STING receptor agonists.

Microbicide

Microbicides are products that can be applied to vaginal or rectal mucosal surfaces with the goal of preventing, or at least significantly reducing, the transmission of sexually transmitted infections. Here is the latest research on microbicides.