Effects of Electrode-Molecule Binding and Junction Geometry on the Single-Molecule Conductance of bis-2,2':6',2″-Terpyridine-based Complexes

Inorganic Chemistry
Ross DavidsonPaul J Low

Abstract

The single molecule conductances of a series of bis-2,2':6',2″-terpyridine complexes featuring Ru(II), Fe(II), and Co(II) metal ions and trimethylsilylethynyl (Me3SiC≡C-) or thiomethyl (MeS-) surface contact groups have been determined. In the absence of electrochemical gating, these complexes behave as tunneling barriers, with conductance properties determined more by the strength of the electrode-molecule contact and the structure of the "linker" than the nature of the metal-ion or redox properties of the complex.

References

Oct 28, 1996·Physical Review Letters·J P PerdewM Ernzerhof
Jun 18, 2002·Nature·Jiwoong ParkDaniel C Ralph
Jun 18, 2002·Nature·Wenjie LiangHongkun Park
Aug 22, 2002·Journal of the American Chemical Society·Alexandr MarchenkoMax Malacria
Jun 10, 2003·Chemistry : a European Journal·Nathalie KatsonisMax Malacria
Dec 11, 2003·Journal of the American Chemical Society·Wolfgang HaissRichard J Nichols
Aug 12, 2005·Dalton Transactions : an International Journal of Inorganic Chemistry·Paul J Low
Sep 24, 2005·Nano Letters·Tim AlbrechtJohannes G Vos
May 18, 2006·Journal of the American Chemical Society·Tim AlbrechtJens Ulstrup
Jul 28, 2006·Angewandte Chemie·I-Wen Peter ChenShie-Ming Peng
Aug 25, 2006·Nature·Latha VenkataramanMichael L Steigerwald
Nov 17, 2006·Chemical Communications : Chem Comm·Geoffrey J AshwellColin J Lambert
Dec 21, 2006·Journal of the American Chemical Society·Tim AlbrechtJens Ulstrup
Feb 28, 2007·The Journal of Organic Chemistry·Masaru EndouYoshio Aso
Oct 20, 2007·Science·Robert L Whetten, Ryan C Price
Nov 2, 2007·Nature Materials·Wei Lu, Charles M Lieber
Jun 3, 2008·Chemphyschem : a European Journal of Chemical Physics and Physical Chemistry·Hongmei LiuHua Zhang
Jun 19, 2008·Journal of the American Chemical Society·Gita SedghiRichard J Nichols
Nov 20, 2008·Small·Mario RubenFerdinand Evers
Oct 15, 2009·Journal of the American Chemical Society·Changsheng WangColin J Lambert
Dec 8, 2009·Nature Nanotechnology·Lorena WelteJulio Gómez-Herrero
Apr 29, 2010·Journal of the American Chemical Society·M KamenetskaL Venkataraman
May 8, 2010·Physical Chemistry Chemical Physics : PCCP·Richard J NicholsDonald Bethell
Aug 10, 2010·Physical Chemistry Chemical Physics : PCCP·Sang Uck LeeYoshiyuki Kawazoe
Oct 12, 2010·Chemistry : a European Journal·Gorka PeraPilar Cea
Oct 12, 2010·Coordination Chemistry Reviews·Matthew JurowCharles Michael Drain
Feb 23, 2012·Journal of the American Chemical Society·Veerabhadrarao KaliginediThomas Wandlowski
May 23, 2012·Nature Chemistry·Hannu Häkkinen
Jun 30, 2012·Langmuir : the ACS Journal of Surfaces and Colloids·Christoph H-H TraulsenChristoph A Schalley
Oct 30, 2012·Dalton Transactions : an International Journal of Inorganic Chemistry·Santiago Marqués-GonzálezPaul J Low
Apr 11, 2013·Chemical Society Reviews·Chuancheng Jia, Xuefeng Guo
Jul 16, 2013·Dalton Transactions : an International Journal of Inorganic Chemistry·Stéphane Rigaut
Sep 3, 2013·Chemical Communications : Chem Comm·Daniel DeBrincatJohn E McGrady
Dec 18, 2013·Advanced Materials·Chiara MusumeciPaolo Samorì
Jan 8, 2014·Nature Communications·Fanben MengXiaodong Chen
Mar 7, 2014·Chemistry : a European Journal·Murat GulcurThomas Wandlowski
May 17, 2014·Journal of the American Chemical Society·Julia PonceEugenio Coronado
Jul 9, 2014·Journal of the American Chemical Society·Brian CapozziLuis M Campos

❮ Previous
Next ❯

Citations

Nov 30, 2016·Chemistry : a European Journal·Sören BockPaul J Low
Sep 25, 2018·Dalton Transactions : an International Journal of Inorganic Chemistry·Cláudio N Verani

❮ Previous
Next ❯

Related Concepts

Trending Feeds

COVID-19

Coronaviruses encompass a large family of viruses that cause the common cold as well as more serious diseases, such as the ongoing outbreak of coronavirus disease 2019 (COVID-19; formally known as 2019-nCoV). Coronaviruses can spread from animals to humans; symptoms include fever, cough, shortness of breath, and breathing difficulties; in more severe cases, infection can lead to death. This feed covers recent research on COVID-19.

Blastomycosis

Blastomycosis fungal infections spread through inhaling Blastomyces dermatitidis spores. Discover the latest research on blastomycosis fungal infections here.

Nuclear Pore Complex in ALS/FTD

Alterations in nucleocytoplasmic transport, controlled by the nuclear pore complex, may be involved in the pathomechanism underlying multiple neurodegenerative diseases including Amyotrophic Lateral Sclerosis and Frontotemporal Dementia. Here is the latest research on the nuclear pore complex in ALS and FTD.

Applications of Molecular Barcoding

The concept of molecular barcoding is that each original DNA or RNA molecule is attached to a unique sequence barcode. Sequence reads having different barcodes represent different original molecules, while sequence reads having the same barcode are results of PCR duplication from one original molecule. Discover the latest research on molecular barcoding here.

Chronic Fatigue Syndrome

Chronic fatigue syndrome is a disease characterized by unexplained disabling fatigue; the pathology of which is incompletely understood. Discover the latest research on chronic fatigue syndrome here.

Evolution of Pluripotency

Pluripotency refers to the ability of a cell to develop into three primary germ cell layers of the embryo. This feed focuses on the mechanisms that underlie the evolution of pluripotency. Here is the latest research.

Position Effect Variegation

Position Effect Variagation occurs when a gene is inactivated due to its positioning near heterochromatic regions within a chromosome. Discover the latest research on Position Effect Variagation here.

STING Receptor Agonists

Stimulator of IFN genes (STING) are a group of transmembrane proteins that are involved in the induction of type I interferon that is important in the innate immune response. The stimulation of STING has been an active area of research in the treatment of cancer and infectious diseases. Here is the latest research on STING receptor agonists.

Microbicide

Microbicides are products that can be applied to vaginal or rectal mucosal surfaces with the goal of preventing, or at least significantly reducing, the transmission of sexually transmitted infections. Here is the latest research on microbicides.