Efficient synthesis of cyclic P-stereogenic phosphinamides from acyclic chiral precursors via radical oxidative intramolecular aryl C-H phosphinamidation

Chemical Communications : Chem Comm
Yuan-Hui ChenFu-She Han

Abstract

We present a highly efficient method for the synthesis of cyclic P-stereogenic phosphinamides via the Ce(IV)-promoted radical oxidative aryl C-H phosphinamidation of acyclic P-stereogenic phosphinamides. The new protocol provides a useful platform for the versatile synthesis of various potentially useful P-stereogenic compounds.

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Citations

Jul 21, 2021·Journal of the American Chemical Society·Xu-Teng LiuQing-Wei Zhang
Oct 8, 2019·Journal of the American Chemical Society·Xu-Teng LiuQing-Wei Zhang
Aug 14, 2019·The Journal of Organic Chemistry·Yan-Na MaXuenian Chen
Oct 8, 2021·Chemical Record : an Official Publication of the Chemical Society of Japan ... [et Al.]·Yan GaoYan-Na Ma
Nov 3, 2021·Chemical Communications : Chem Comm·Jupil ParkYoung S Park
Dec 28, 2021·The Journal of Organic Chemistry·Wenchao GaoSheng Zhang

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