Efficient uptake of dimethyl sulfoxide by the desoxomolybdenum(IV) dithiolate complex containing bulky hydrophobic groups

Dalton Transactions : an International Journal of Inorganic Chemistry
Yuki HasenakaKiyotaka Onitsuka

Abstract

A desoxomolybdenum(IV) complex containing bulky hydrophobic groups and NH···S hydrogen bonds, (Et4N)[Mo(IV)(OSi(t)BuPh2)(1,2-S2-3,6-{(4-(t)BuC6H4)3CCONH}2C6H2)2], was synthesized. This complex promotes the oxygen-atom-transfer (OAT) reaction of DMSO by efficient uptake of the substrate into the active center. The clean OAT reaction of Me3NO is also achieved.

References

Feb 19, 1998·Journal of Molecular Biology·A S McAlpineS Bailey
Dec 25, 2007·Acta Crystallographica. Section A, Foundations of Crystallography·George M Sheldrick
May 25, 2011·Coordination Chemistry Reviews·Partha Basu, Sharon J N Burgmayer
Jan 29, 2014·Chemical Reviews·Russ HillePartha Basu

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Citations

Jun 16, 2015·Dalton Transactions : an International Journal of Inorganic Chemistry·Yuki HasenakaKiyotaka Onitsuka
Apr 16, 2020·Journal of the American Chemical Society·Mikiyas K AssefaTrevor W Hayton

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