Efficient visible light-driven water oxidation catalysed by an iron(iv) clathrochelate complex

Chemical Communications : Chem Comm
Sergii I ShylinIgor O Fritsky

Abstract

A water-stable FeIV clathrochelate complex catalyses fast and homogeneous photochemical oxidation of water to dioxygen with a turnover frequency of 2.27 s-1 and a maximum turnover number of 365. An FeV intermediate generated under catalytic conditions is trapped and characterised using EPR and Mössbauer spectroscopy.

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Citations

Oct 18, 2019·Photochemical & Photobiological Sciences : Official Journal of the European Photochemistry Association and the European Society for Photobiology·Md Ali AsrafFrancis Verpoort
Sep 17, 2020·International Journal of Molecular Sciences·Kelvin Suggs, Alfred Z Msezane
Apr 8, 2021·Inorganic Chemistry·Ivan S GolovanovAlexey Yu Sukhorukov
May 7, 2021·Acta Crystallographica. Section E, Crystallographic Communications·Maksym O PlutenkoNurullo U Mulloev
Oct 6, 2021·Chemical Communications : Chem Comm·Sergii I ShylinIgor O Fritsky

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