"Eggs in egg cartons": co-crystallization to embed molecular cages into crystalline lattices.

Chemical Science
Yuya DomotoMakoto Fujita

Abstract

Discrete (M3L2) n cages assembled from a tripodal ligand (L) and metal ions (M: Cu(i) or Ag(i)) are embedded in networked coordination hosts formed by partial dissociation of the same discrete cages during the crystallization process. The resulting "eggs-in-an-egg-carton" structures provide unique examples of the co-crystallization of discrete and infinite coordination frameworks.

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Citations

Jun 9, 2021·Journal of the American Chemical Society·Yuya DomotoMakoto Fujita
Aug 8, 2021·Molecules : a Journal of Synthetic Chemistry and Natural Product Chemistry·Guoping ChenKatsuhiko Ariga
Aug 15, 2021·Nature Chemistry·Andrew W HeardJonathan R Nitschke

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Methods Mentioned

BETA
X-ray
co-crystallization

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