Electrocatalytic oxidation of ethanol and ethylene glycol on cubic, octahedral and rhombic dodecahedral palladium nanocrystals

Chemical Communications : Chem Comm
Xian-Yin MaWen-Bin Cai

Abstract

Cubic, octahedral and rhombic dodecahedral Pd nanocrystals were synthesized and examined as nanocatalysts for electro-oxidation of ethanol and ethylene glycol. Combined electrochemical measurements and density functional theory calculations reveal that nanofacet-dependent affinity and reactivity of OHadsand COadsare closely linked to the C2 alcohol oxidation activities, with the highest reactivity found on the Pd nanocubes bounded by {100} facets.

References

Aug 2, 2011·Chemistry : a European Journal·Jiawei ZhangLansun Zheng
Apr 11, 2012·Chemical Society Reviews·Hairong YueJinlong Gong
Jul 17, 2012·Chemical Communications : Chem Comm·Han-Xuan ZhangWen-Bin Cai
Apr 12, 2014·Physical Chemistry Chemical Physics : PCCP·Jia-Mei JinWen-Feng Lin
May 2, 2014·Chemphyschem : a European Journal of Chemical Physics and Physical Chemistry·Carlos Busó-RogeroJuan M Feliu

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Citations

Mar 6, 2019·ChemSusChem·Juan BaiYu Chen
Mar 14, 2020·ACS Applied Materials & Interfaces·Yang YangQingsheng Gao
Sep 26, 2019·ACS Applied Materials & Interfaces·Muhammad IqbalYusuke Yamauchi

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Methods Mentioned

BETA
transmission electron microscopy

Software Mentioned

EGOR

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