Electrocatalytic reduction of CO2 by thiophene-substituted rhenium(i) complexes and by their polymerized films

Dalton Transactions : an International Journal of Inorganic Chemistry
Cunfa SunCarlo Nervi

Abstract

Three novel thiophene substituted bipyridine ligands and their corresponding rhenium complexes were synthesized and tested for the electrocatalytic reduction of CO2. Two complexes underwent oxidative electropolymerization on a glassy carbon electrode (GCE) surface. The conductive polymers chemically deposited on the GCE allow electron transport from the surface to the polymer-attached rhenium catalytic center in contact with the solution. The chemically modified electrodes show significant catalytic activities for CO2 reduction, and moderate relative higher stabilities when compared with the homogeneous solution counterparts.

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Citations

Dec 21, 2016·Journal of the American Chemical Society·Kate M WaldieRobert M Waymouth
Aug 24, 2017·Chemphyschem : a European Journal of Chemical Physics and Physical Chemistry·Cunfa SunCarlo Nervi
Apr 13, 2019·Physical Chemistry Chemical Physics : PCCP·Xiaoli WangFang Huang
Apr 7, 2017·Chemphyschem : a European Journal of Chemical Physics and Physical Chemistry·Dogukan Hazar ApaydinNiyazi Serdar Sariciftci
Jun 11, 2020·Dalton Transactions : an International Journal of Inorganic Chemistry·Lucas A PaulInke Siewert
May 28, 2020·Dalton Transactions : an International Journal of Inorganic Chemistry·Breno L SouzaAntonio Otavio T Patrocinio
Jan 22, 2021·Dalton Transactions : an International Journal of Inorganic Chemistry·Ahmed M MansourOla R Shehab
Jul 3, 2021·Polymers·Lorenzo VallanDaniele Mantione

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