Electrochemical calcium extraction from 1D-Ca3 Co2 O6

Dalton Transactions : an International Journal of Inorganic Chemistry
Deyana S TchitchekovaM Rosa Palacín

Abstract

The electrochemical oxidation of a transition metal oxide through calcium extraction is achieved for the first time. The 1D framework of Ca3Co2O6 is maintained upon oxidation and the new phase formed exhibits a modulated structure. The process occurs at high potential and is partially reversible, which opens prospects for a calcium battery proof-of-concept.

References

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Oct 25, 2014·Chemical Reviews·John MuldoonThomas Gregory
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Citations

Feb 13, 2020·Dalton Transactions : an International Journal of Inorganic Chemistry·Ashley P BlackM Elena Arroyo-de Dompablo
Mar 8, 2019·Frontiers in Chemistry·Damien MontiM Rosa Palacín
Jul 20, 2021·Energy & Fuels : an American Chemical Society Journal·A P BlackM R Palacin
Aug 29, 2019·ACS Omega·Roberta VerrelliM Rosa Palacín
Oct 30, 2019·Chemical Reviews·M Elena Arroyo-de DompabloM Rosa Palacín
Nov 19, 2019·Chemistry of Materials : a Publication of the American Chemical Society·Romain DugasAlexandre Ponrouch

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Methods Mentioned

BETA
scanning electron microscopy
X-ray

Software Mentioned

Jana2006

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