Electrochemical oxidation of aliphatic amines and their attachment to carbon and metal surfaces

Langmuir : the ACS Journal of Surfaces and Colloids
Alain AdenierNeus Vilà

Abstract

The electrochemical oxidation of aliphatic amines (primary, secondary, and tertiary) has been investigated by cyclic voltammetry and preparative electrolysis. The oxidation mechanisms have been established, and the lifetimes of the radical cations have been measured for secondary and tertiary amines. These results have been put in parallel with the attachment of amines to glassy carbon, Au, and Pt electrodes by cyclic voltammetry, X-ray photoelectron spectroscopy (XPS), and infrared reflection-absorption spectroscopy (IRRAS). It is then possible to show that it is not the radical cation but the radical obtained after the deprotonation which reacts with the electrode surface. XPS results also point to the existence of a covalent bond between Au or Pt and the organic moiety.

References

Jul 17, 1998·Analytical Chemistry·W B NowallW G Kuhr
Jun 15, 1993·Physical Review. B, Condensed Matter·F M LeibsleA W Robinson
Jul 18, 2001·Journal of the American Chemical Society·A AdenierF Podvorica
Nov 26, 2002·The Journal of Organic Chemistry·Estelle CoulonJean-Pierre Pulicani
Dec 4, 2003·Journal of the American Chemical Society·Claude P Andrieux, Jean Pinson

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Citations

Oct 11, 2012·Journal of the American Chemical Society·Aleksandra PinczewskaPhilip N Bartlett
Oct 1, 2009·Journal of the American Chemical Society·Kristoffer MalmosKim Daasbjerg
Jul 2, 2009·Chemical Communications : Chem Comm·Olivier Baslé, Chao-Jun Li
Apr 13, 2011·Chemical Communications : Chem Comm·Li ZhangZhiyong Wang
Mar 20, 2012·Physical Chemistry Chemical Physics : PCCP·Pradipta PurkayasthaPrasun Ghosh
Dec 23, 2011·Langmuir : the ACS Journal of Surfaces and Colloids·E Kate WalkerKeith J Stevenson
Jul 17, 2012·Langmuir : the ACS Journal of Surfaces and Colloids·Alice MesnageSerge Palacin
Sep 6, 2012·Langmuir : the ACS Journal of Surfaces and Colloids·Gobind S BishtMarc Madou
Feb 13, 2013·Langmuir : the ACS Journal of Surfaces and Colloids·Lita LeeAlison J Downard
Apr 20, 2011·Chemical Society Reviews·Daniel Bélanger, Jean Pinson
Jun 1, 2012·Chemical Society Reviews·Ali CoskunJ Fraser Stoddart
Dec 5, 2015·Chemistry : a European Journal·Jessica GroppiJeremy D Kilburn
Nov 30, 2010·Biosensors & Bioelectronics·Agata KowalczykZbigniew Stojek
Mar 5, 2016·Analytical and Bioanalytical Chemistry·Shimeles Addisu KitteGuobao Xu
Jul 16, 2010·Angewandte Chemie·James J DeveryRobert A Flowers
Nov 26, 2013·Angewandte Chemie·Julie BroggiPatrice Vanelle
Sep 22, 2015·The Journal of Organic Chemistry·Matthieu KoepfRobert H Crabtree
Apr 25, 2015·Chemistry : a European Journal·Yuanzheng ChengShouyun Yu
Jul 18, 2015·Langmuir : the ACS Journal of Surfaces and Colloids·Christine L Chevalier, Elizabeth C Landis
Jul 10, 2012·Artificial DNA, PNA & XNA·Chiara ZanardiStefano Maiorana
Nov 30, 2013·Biosensors & Bioelectronics·Agata KowalczykAnna M Nowicka
Dec 20, 2012·Dalton Transactions : an International Journal of Inorganic Chemistry·David A McMorranKeith C Gordon
May 17, 2014·Nanoscale·Xiao-Fei ZhouRichard G Compton
Sep 11, 2016·Materials Science & Engineering. C, Materials for Biological Applications·Leili DaneshvarSomayeh Tarahomi

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