Electrochromic bis(terpyridine)metal complex nanosheets

Journal of the American Chemical Society
Kenji TakadaHiroshi Nishihara

Abstract

A series of electrochromic metal complex nanosheets comprising 1,3,5-tris(4-(2,2':6',2″-terpyridyl)phenyl)benzene or 1,3,5-tris((2,2':6',2″-terpyridyl)ethynyl)benzene and Fe(2+) or Co(2+) was synthesized. The preparation of multilayered nanosheets was achieved by liquid/liquid interfacial synthesis using an organic ligand solution and an aqueous metal-ion solution. The resultant nanosheet had a flat, smooth morphology and was several hundreds of nanometers thick. Upon its deposition on an indium tin oxide (ITO) electrode, the nanosheet underwent a reversible and robust redox reaction (Fe(3+)/Fe(2+) or Co(2+)/Co(+)) accompanied by a distinctive color change. Electrochromism was achieved in a solidified device composed of the nanosheet, a pair of ITO electrodes, and a polymer-supported electrolyte. The combination of Fe(2+) and Co(2+) nanosheets in one device-deposited on each ITO electrode-demonstrated dual-electrochromic behavior.

References

May 6, 2004·Journal of the American Chemical Society·Nobuyuki SakaiTakayoshi Sasaki
Oct 23, 2004·Science·K S NovoselovA A Firsov
Jun 2, 2006·Angewandte Chemie·Sayoko NagashimaHiroshi Nishihara
Mar 31, 2007·Journal of the American Chemical Society·Renzhi MaTakayoshi Sasaki
Nov 9, 2007·Chemical Communications : Chem Comm·Kosuke NamikiHiroshi Nishihara
Mar 26, 2009·Dalton Transactions : an International Journal of Inorganic Chemistry·Nadezhda M LogachevaVladimir V Chernyshev
Jun 1, 2010·Nature Materials·Rie MakiuraHiroshi Kitagawa
Feb 5, 2011·Science·Jonathan N ColemanValeria Nicolosi
Apr 1, 2011·Journal of the American Chemical Society·Soichiro MotoyamaHiroshi Kitagawa
Jul 5, 2011·Angewandte Chemie·Thomas BauerA Dieter Schlüter
Jan 14, 2012·Journal of the American Chemical Society·Egle PuodziukynaiteJohn R Reynolds
Oct 10, 2012·Journal of the American Chemical Society·Lioz EtgarMichael Grätzel
Dec 12, 2012·Angewandte Chemie·Thiruvelu BhuvanaEunkyoung Kim
Jan 31, 2013·Journal of the American Chemical Society·Tetsuya KambeHiroshi Nishihara
Mar 29, 2014·Journal of the American Chemical Society·Zhikun ZhengA Dieter Schlüter
Dec 18, 2014·Journal of the American Chemical Society·Ryota SakamotoHiroshi Nishihara
Apr 4, 2015·Nature Communications·Ryota SakamotoHiroshi Nishihara

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Citations

Feb 27, 2016·Langmuir : the ACS Journal of Surfaces and Colloids·Hiroaki MaedaHiroshi Nishihara
Apr 15, 2016·Chemical Reviews·Yubin DingYongshu Xie
May 11, 2016·ACS Applied Materials & Interfaces·Rakesh K PandeyMasayoshi Higuchi
Jan 28, 2017·Langmuir : the ACS Journal of Surfaces and Colloids·Wenyang DaiA Dieter Schlüter
Jan 14, 2017·Journal of the American Chemical Society·Ralph Z LangeA Dieter Schlüter
Feb 16, 2017·Journal of the American Chemical Society·Ryota MatsuokaHiroshi Nishihara
Mar 23, 2017·Journal of the American Chemical Society·Takamasa TsukamotoHiroshi Nishihara
May 12, 2017·Chemical Communications : Chem Comm·Ryota SakamotoHiroshi Nishihara
Apr 19, 2017·Chemistry : a European Journal·Amalia RapakousiouHiroshi Nishihara
May 12, 2017·Inorganic Chemistry·Ryo OhtaniShinya Hayami
May 31, 2017·Journal of the American Chemical Society·Zhe ZhangXiaopeng Li
Dec 19, 2016·Advanced Materials·Takahiro FukinoTakuzo Aida
Mar 7, 2017·Dalton Transactions : an International Journal of Inorganic Chemistry·Ryo OhtaniShinya Hayami
Feb 2, 2017·Chemical Communications : Chem Comm·Takamasa TsukamotoHiroshi Nishihara
Dec 25, 2015·Chemical Communications : Chem Comm·Michael MorozovMilko E van der Boom
May 24, 2018·Dalton Transactions : an International Journal of Inorganic Chemistry·Yifan LinTakayoshi Sasaki
Jun 12, 2018·Angewandte Chemie·Vivian MüllerA Dieter Schlüter
Nov 18, 2015·Chemistry : a European Journal·Masako KatoAtsushi Kobayashi
May 31, 2018·Angewandte Chemie·Xinliang Feng, A Dieter Schlüter
Mar 14, 2019·Chemistry : a European Journal·Masaki YoshidaMasako Kato
May 28, 2019·Philosophical Transactions. Series A, Mathematical, Physical, and Engineering Sciences·Ryuichi MuraseDeanna M D'Alessandro
Jun 22, 2019·Advanced Materials·Ryota SakamotoHiroshi Nishihara
Dec 13, 2019·Chemical Communications : Chem Comm·Satya Ranjan Jena, Joyanta Choudhury
Jul 20, 2016·Advanced Materials·Yan HuangChunyi Zhi
Jan 15, 2019·Dalton Transactions : an International Journal of Inorganic Chemistry·Ryo OhtaniShinya Hayami
Apr 25, 2018·Dalton Transactions : an International Journal of Inorganic Chemistry·Alok Kumar SinghVikram Singh
Aug 31, 2019·Beilstein Journal of Nanotechnology·Katsuhiko ArigaLok Kumar Shrestha
Aug 17, 2020·Scientific Reports·Ryo AraiHiroshi Nishihara
Sep 29, 2019·Dalton Transactions : an International Journal of Inorganic Chemistry·Yu KuaiCheng Zhang
Sep 5, 2020·Angewandte Chemie·Ji-Fei FengRong Cao
Oct 21, 2020·Chemical Society Reviews·Guojian YangSean Xiao-An Zhang
Oct 27, 2020·Dalton Transactions : an International Journal of Inorganic Chemistry·Radosław BanaszMonika Wałęsa-Chorab
Nov 13, 2020·Dalton Transactions : an International Journal of Inorganic Chemistry·Ya-Ping OuSheng Hua Liu

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