Electronic Spectra of Protonated Fluoranthene in a Neon Matrix and Gas Phase at 10 K

The Journal of Physical Chemistry. a
Arghya ChakrabortyJohn P Maier

Abstract

Four electronic systems with origin bands at 759.5, 559.3, 476.3, and 385.5 nm are detected in a 6 K neon matrix following deposition of mass-selected protonated fluoranthene C16H11(+) produced from a reaction of neutral vapor and ethanol in a hot-cathode ion source. Two cationic isomers are identified as the carriers of these band systems. The 559.3, 476.3, and 385.5 nm absorptions are assigned to 4,3,2 (1)A' ← X (1)A' transitions of isomer E(+) (γ-) and the 2 (1)A' ← X (1)A' system at 759.5 nm is of isomer C(+) (α-) of protonated fluoranthene on the basis of theoretical predictions. The electronic spectrum of E(+) was also recorded in the gas phase using a resonant 1 + 1 two-photon excitation-dissociation technique in an ion trap at vibrational and rotational temperatures of 10 K. The 3,2 (1)A' ← X (1)A' transitions have origin band maxima at 558.28 ± 0.01 and 474.92 ± 0.01 nm. Both the 2 (1)A' and 3 (1)A' excited states have a distinct vibrational pattern with lifetimes on the order of 1 ps.

References

May 10, 2001·Spectrochimica Acta. Part A, Molecular and Biomolecular Spectroscopy·D M HudginsL J Allamandola
Aug 25, 2011·The Journal of Physical Chemistry. a·Iryna GarkushaJohn P Maier
Sep 30, 2014·The Journal of Physical Chemistry. a·F-X HardyJ P Maier
Mar 20, 2014·The Journal of Physical Chemistry Letters·C A RiceJ P Maier

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Citations

Jan 11, 2019·Physical Chemistry Chemical Physics : PCCP·Arghya Chakraborty, Yuan-Pern Lee

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