Electronic Structure of Copper Corroles

Angewandte Chemie
Christopher M LemonDaniel G Nocera

Abstract

The ground state electronic structure of copper corroles has been a topic of debate and revision since the advent of corrole chemistry. Computational studies formulate neutral Cu corroles with an antiferromagnetically coupled Cu(II) corrole radical cation ground state. X-ray photoelectron spectroscopy, EPR, and magnetometry support this assignment. For comparison, Cu(II) isocorrole and [TBA][Cu(CF3)4] were studied as authentic Cu(II) and Cu(III) samples, respectively. In addition, the one-electron reduction and one-electron oxidation processes are both ligand-based, demonstrating that the Cu(II) centre is retained in these derivatives. These observations underscore ligand non-innocence in copper corrole complexes.

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Feb 26, 2015·Inorganic Chemistry·Christopher M LemonDaniel G Nocera
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Sep 25, 2015·Faraday Discussions·Christopher M Lemon, Daniel G Nocera

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Citations

Aug 18, 2016·Inorganic Chemistry·Shota OoiAtsuhiro Osuka
Dec 24, 2016·Chemical Reviews·Yuanyuan FangKarl M Kadish
Dec 21, 2016·Dalton Transactions : an International Journal of Inorganic Chemistry·Jessica A ZieglerJohn Arnold
Jul 21, 2017·Dalton Transactions : an International Journal of Inorganic Chemistry·Pinky YadavKarl M Kadish
Jul 26, 2017·Journal of the American Chemical Society·Violaine GoudyGrégory Nocton
Oct 19, 2017·Chemistry : a European Journal·Biju BasumataryJeyaraman Sankar
Oct 6, 2017·Chemistry : a European Journal·Irene Mustieles MarínAudrey Auffrant
Jun 27, 2018·Dalton Transactions : an International Journal of Inorganic Chemistry·Casey N BrodskyDaniel G Nocera
Aug 18, 2017·Angewandte Chemie·Liam S SharninghausenRobert H Crabtree
May 17, 2019·Angewandte Chemie·Miguel BayaBabil Menjón
Apr 21, 2018·Chemical Science·Daiki Shimizu, Atsuhiro Osuka
Feb 15, 2019·Molecules : a Journal of Synthetic Chemistry and Natural Product Chemistry·Kento UetaAtsuhiro Osuka
Oct 31, 2018·Chemistry, an Asian Journal·Shota OoiAtsuhiro Osuka
Sep 4, 2019·Dalton Transactions : an International Journal of Inorganic Chemistry·Manuela StefanelliRoberto Paolesse
Sep 25, 2019·Dalton Transactions : an International Journal of Inorganic Chemistry·Wangyang MaQing Ye
Dec 17, 2020·Chemical Communications : Chem Comm·Fan WuZhen Shen
Apr 8, 2021·Chemistry : a European Journal·Çağla BaşMartin Bröring
Apr 17, 2018·Inorganic Chemistry·Christopher M LemonDaniel G Nocera
Feb 23, 2017·Chemical Reviews·Joana F B BarataJosé A S Cavaleiro
Mar 13, 2018·Journal of the American Chemical Society·Patrick W Smith, T Don Tilley
May 12, 2018·Journal of the American Chemical Society·Yogesh Kumar MauryaHiroyuki Furuta
Jan 18, 2018·Inorganic Chemistry·Xiaoqin JiangKarl M Kadish

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