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Electronic Structure of Tetracyanonickelate(II)

Inorganic Chemistry

Nov 18, 2019

Julius OppenheimHarry B. Gray

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Abstract

Tetracyanonickelate(II) has been a poster child of ligand field theory for several decades. We have revisited the literature assignments of the absorption spectrum of [Ni(CN)4]2- and the calculated ordering of orbitals with metal d character. Using low-temperature single-crystal absorpt...read more

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Ligands
Literature
Metals
Nickel
Tetracyanonickelate
Mycoplasma ovipneumoniae
Dementia of Frontal Lobe Type
Structure
A & D
Coelichneumon orbitator
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Electronic Structure of Tetracyanonickelate(II)

Inorganic Chemistry

Nov 18, 2019

Julius OppenheimHarry B. Gray

PMID: 31697485

DOI: 10.1021/acs.inchem.9b02135

Abstract

Tetracyanonickelate(II) has been a poster child of ligand field theory for several decades. We have revisited the literature assignments of the absorption spectrum of [Ni(CN)4]2- and the calculated ordering of orbitals with metal d character. Using low-temperature single-crystal absorpt...read more

Mentioned in this Paper

Ligands
Literature
Metals
Nickel
Tetracyanonickelate

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