Electrons, Excitons, and Phonons in Two-Dimensional Hybrid Perovskites: Connecting Structural, Optical, and Electronic Properties

The Journal of Physical Chemistry Letters
Daniel B Straus, Cherie R Kagan

Abstract

Two-dimensional (2D) hybrid perovskites are stoichiometric compounds consisting of alternating inorganic metal-halide sheets and organoammonium cationic layers. This materials class is widely tailorable in composition, structure, and dimensionality and is providing an intriguing playground for the solid-state chemistry and physics communities to uncover structure-property relationships. In this Perspective, we describe semiconducting 2D perovskites containing lead and tin halide inorganic frameworks. In these 2D perovskites, charges are typically confined to the inorganic framework because of strong quantum and dielectric confinement effects, and exciton binding energies are many times greater than kT at room temperature. We describe the role of the heavy atoms in the inorganic framework; the geometry and chemistry of organic cations; and the "softness" of the organic-inorganic lattice on the electronic structure and dynamics of electrons, excitons, and phonons that govern the physical properties of these materials.

References

Sep 15, 1988·Physical Review. B, Condensed Matter·S CharbonneauB Elman
Dec 15, 1989·Physical Review. B, Condensed Matter·M Kumagai, T Takagahara
Nov 15, 1990·Physical Review. B, Condensed Matter·L C Andreani, A Pasquarello
Dec 15, 1990·Physical Review. B, Condensed Matter·T IshiharaT Goto
Jan 15, 1991·Physical Review. B, Condensed Matter·X F He
Sep 15, 1991·Physical Review. B, Condensed Matter·A M FoxW Y Jan
Mar 15, 1992·Physical Review. B, Condensed Matter·X HongA V Nurmikko
Aug 15, 1992·Physical Review. B, Condensed Matter·H MathieuP Christol
Oct 14, 2003·Inorganic Chemistry·Zhengtao Xu, David B Mitzi
Jun 21, 2005·Inorganic Chemistry·Jeremy L KnutsonDavid B Mitzi
Jan 16, 2014·Journal of the American Chemical Society·Emma R DohnerHemamala I Karunadasa
Aug 28, 2014·Journal of the American Chemical Society·Emma R DohnerHemamala I Karunadasa
Sep 10, 2014·Angewandte Chemie·Ian C SmithHemamala I Karunadasa
Jan 21, 2015·Journal of the American Chemical Society·Xiaoxi WuX-Y Zhu
Apr 4, 2015·The Journal of Physical Chemistry. C, Nanomaterials and Interfaces·Aron Walsh
May 29, 2015·Journal of the American Chemical Society·Duyen H CaoMercouri G Kanatzidis
Aug 16, 2015·The Journal of Physical Chemistry Letters·Gaëtan LantyEmmanuelle Deleporte
Nov 14, 2015·ACS Nano·Michael A SusnerPetro Maksymovych
Apr 5, 2016·Chemical Reviews·Bayrammurad Saparov, David B Mitzi
May 27, 2016·Nature Communications·Adam D WrightLaura M Herz
Jul 8, 2016·Nature·Hsinhan TsaiMercouri G Kanatzidis
Aug 16, 2016·The Journal of Physical Chemistry Letters·Octavi E SemoninJonathan S Owen
Sep 9, 2016·Advanced Materials·Toshinori MatsushimaChihaya Adachi
Oct 1, 2016·Nano Letters·Rebecca L MilotLaura M Herz
Oct 7, 2016·Journal of the American Chemical Society·Daniel B StrausCherie R Kagan
Oct 25, 2016·ACS Nano·Laurent PedesseauMikaël Kepenekian
Feb 28, 2017·Nano Letters·Giselle A ElbazXavier Roy
May 5, 2017·Nature Communications·Archana RajaAlexey Chernikov
Jul 1, 2017·The Journal of Physical Chemistry Letters·Mikaël Kepenekian, Jacky Even
Jun 1, 2015·Chemical Science·Gregor KieslichAnthony K Cheetham
Oct 12, 2017·ACS Nano·Claudiu M IaruAndrei Yu Silov

❮ Previous
Next ❯

Citations

Aug 14, 2018·Chemical Society Reviews·Kun ChenHarun Tüysüz
Nov 30, 2018·Physical Chemistry Chemical Physics : PCCP·Jesús Rodríguez-RomeroEva M Barea
Jan 31, 2019·ChemSusChem·Carmen Ortiz-CervantesDiego Solis-Ibarra
Jun 11, 2019·Nanoscale·Fei Yan, Hilmi Volkan Demir
Sep 12, 2018·Beilstein Journal of Nanotechnology·Oleksandr Stroyuk
Feb 3, 2020·The Journal of Chemical Physics·Shibin DengLibai Huang
Oct 3, 2019·Physical Chemistry Chemical Physics : PCCP·Zhi-Gang Yu
Feb 18, 2020·Frontiers in Chemistry·Inés García-BenitoGiulia Grancini
Jan 16, 2019·Nature Materials·Félix ThouinAjay Ram Srimath Kandada
Apr 29, 2020·Nature Communications·Michael SeitzFerry Prins
Sep 6, 2019·Dalton Transactions : an International Journal of Inorganic Chemistry·Naveen R VenkatesanRam Seshadri
Feb 9, 2021·The Journal of Physical Chemistry Letters·Mateusz DyksikPaulina Plochocka
Nov 4, 2020·The Journal of Chemical Physics·Ajay Ram Srimath KandadaCarlos Silva
Apr 11, 2020·ACS Nano·Balaji DhanabalanRoman Krahne
Mar 18, 2021·Reports on Progress in Physics·Ziming ChenHin-Lap Yip
Jun 18, 2021·ACS Nano·Amrita DeyLakshminarayana Polavarapu
Jul 7, 2021·ACS Applied Materials & Interfaces·Miriam KarpińskaPaulina Plochocka
Apr 14, 2020·Journal of the American Chemical Society·Lingling MaoMercouri G Kanatzidis
Jan 5, 2021·The Journal of Physical Chemistry. C, Nanomaterials and Interfaces·Magnus B FridrikssonFerdinand C Grozema
Apr 23, 2019·The Journal of Physical Chemistry Letters·Tingting NiuWei Huang
Jan 23, 2020·ACS Nano·Junze LiDehui Li
Aug 27, 2019·The Journal of Physical Chemistry Letters·Xuan Trung NguyenAntonietta De Sio

❮ Previous
Next ❯

Related Concepts

Trending Feeds

COVID-19

Coronaviruses encompass a large family of viruses that cause the common cold as well as more serious diseases, such as the ongoing outbreak of coronavirus disease 2019 (COVID-19; formally known as 2019-nCoV). Coronaviruses can spread from animals to humans; symptoms include fever, cough, shortness of breath, and breathing difficulties; in more severe cases, infection can lead to death. This feed covers recent research on COVID-19.

Blastomycosis

Blastomycosis fungal infections spread through inhaling Blastomyces dermatitidis spores. Discover the latest research on blastomycosis fungal infections here.

Nuclear Pore Complex in ALS/FTD

Alterations in nucleocytoplasmic transport, controlled by the nuclear pore complex, may be involved in the pathomechanism underlying multiple neurodegenerative diseases including Amyotrophic Lateral Sclerosis and Frontotemporal Dementia. Here is the latest research on the nuclear pore complex in ALS and FTD.

Applications of Molecular Barcoding

The concept of molecular barcoding is that each original DNA or RNA molecule is attached to a unique sequence barcode. Sequence reads having different barcodes represent different original molecules, while sequence reads having the same barcode are results of PCR duplication from one original molecule. Discover the latest research on molecular barcoding here.

Chronic Fatigue Syndrome

Chronic fatigue syndrome is a disease characterized by unexplained disabling fatigue; the pathology of which is incompletely understood. Discover the latest research on chronic fatigue syndrome here.

Evolution of Pluripotency

Pluripotency refers to the ability of a cell to develop into three primary germ cell layers of the embryo. This feed focuses on the mechanisms that underlie the evolution of pluripotency. Here is the latest research.

Position Effect Variegation

Position Effect Variagation occurs when a gene is inactivated due to its positioning near heterochromatic regions within a chromosome. Discover the latest research on Position Effect Variagation here.

STING Receptor Agonists

Stimulator of IFN genes (STING) are a group of transmembrane proteins that are involved in the induction of type I interferon that is important in the innate immune response. The stimulation of STING has been an active area of research in the treatment of cancer and infectious diseases. Here is the latest research on STING receptor agonists.

Microbicide

Microbicides are products that can be applied to vaginal or rectal mucosal surfaces with the goal of preventing, or at least significantly reducing, the transmission of sexually transmitted infections. Here is the latest research on microbicides.

© 2022 Meta ULC. All rights reserved