Elusive Reaction Intermediates in Solution Explored by ESI-MS: Reverse Periscope for Mechanistic Investigations

Angewandte Chemie
Claudio IacobucciFrancesco De Angelis

Abstract

Just as periscopes allow a submarine to visually search for objects above the surface of the sea, in a reversed periscope fashion electrospray mass spectrometry (ESI-MS) can analyze the compounds at the gas phase/liquid phase interface for chemical entities which may exist in solution. The challenge is the identification and structural characterization of key elusive reaction intermediates in chemical transformations, intermediates which are able to explain how chemical processes occur. This Minireview summarizes recent selected publications on the use of ESI-MS techniques for studying solution intermediates of homogeneous chemical reactions.

References

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Feb 25, 2015·Chemistry : a European Journal·Katharina BöckKonrad Koszinowski

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Citations

Feb 14, 2017·Chemistry : a European Journal·Haoqing ChenZhiling Zhu
May 10, 2017·Angewandte Chemie·Johannes AppunChristoph Schneider
May 19, 2017·Analytical Chemistry·Christopher J PulliamR Graham Cooks
Jun 27, 2017·Physical Chemistry Chemical Physics : PCCP·Edward Matthews, Caroline E H Dessent
Jan 18, 2017·Chemphyschem : a European Journal of Chemical Physics and Physical Chemistry·Guillaume CompainElisabet Duñach
Sep 29, 2019·Chemical Communications : Chem Comm·Gui-Juan ChengXinhao Zhang
Sep 13, 2019·Chemical Communications : Chem Comm·Gilian T ThomasJ Scott McIndoe
Aug 26, 2016·Chemistry : a European Journal·Claudio IacobucciAntony Memboeuf
Mar 9, 2018·Chemistry : a European Journal·Claudio IacobucciFrancesco De Angelis
Jun 9, 2016·Chemistry : a European Journal·Jiří SchulzJana Roithová
Nov 5, 2019·European Journal of Organic Chemistry·Guilherme L TripodiJana Roithová
Jul 19, 2020·Proceedings of the National Academy of Sciences of the United States of America·Sarju AdhikariYu Xia
Nov 24, 2020·Chemistry : a European Journal·Isaac OmariJ Scott McIndoe
Feb 5, 2021·Chemical Record : an Official Publication of the Chemical Society of Japan ... [et Al.]·Marcelo O RodriguesBrenno A D Neto
Mar 27, 2021·The Journal of Physical Chemistry. a·Martin Mayer, Knut R Asmis
Jun 9, 2018·Journal of the American Society for Mass Spectrometry·Ethan M McBride, Guido F Verbeck
Jun 15, 2021·Chemical Science·Jaya Mehara, Jana Roithová
Aug 21, 2018·Journal of the American Chemical Society·Tiankai ChenJianping Xie

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