Enantiomerically Enriched 1,2-P ,N -Bidentate Ferrocenyl Ligands for 1,3-Dipolar Cycloaddition and Transfer Hydrogenation Reactions

Molecules : a Journal of Synthetic Chemistry and Natural Product Chemistry
Irina A UtepovaAndrey P Antonchick

Abstract

Novel complexes of 1,2-P,N-bidentate ferrocenyl ligands with AgOAc or with [RuCl₂(PPh₃)₃] as catalysts have been studied in asymmetric synthesis. The catalytic activity of these systems have been studied in [3+2]-cycloaddition of azomethine ylides with olefins and the asymmetric transfer hydrogenation of ketones.

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Methods Mentioned

BETA
nuclear magnetic resonance
NMR
column chromatography

Software Mentioned

Compass for oTof series
DataAnalysis

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