Enantioselective synthesis of cyclic sulfamidates via Pd-catalyzed hydrogenation

Organic Letters
You-Qing WangYong-Gui Zhou

Abstract

Using Pd(CF3CO2) 2/(S,S)-f-binaphane as the catalyst, an efficient enantioselective synthesis of cyclic sulfamidates was developed via asymmetric hydrogenation of the corresponding cyclic imines in 2,2,2-trifluoroethanol at room temperature with high enantioselectivities (up to 99% ee).

References

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Jul 20, 2002·The Journal of Organic Chemistry·Jeffrey J PosakonyTimothy J Tewson
Mar 14, 2003·Organic Letters·Andrew J WilliamsTimothy Gallagher
Aug 28, 2003·Journal of the American Chemical Society·Wen-Bo WangYong-Gui Zhou
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Dec 4, 2004·Organic Letters·John F BowerTimothy Gallagher
Jul 16, 2005·Organic Letters·You-Qing WangYong-Gui Zhou
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Mar 7, 2006·Angewandte Chemie·Sheng-Mei LuYong-Gui Zhou
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Apr 21, 2007·The Journal of Organic Chemistry·You-Qing WangYong-Gui Zhou
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Citations

Nov 22, 2011·Chemical Reviews·Duo-Sheng WangYong-Gui Zhou
Dec 18, 2013·Chemical Reviews·William Spillane, Jean-Baptiste Malaubier
Mar 25, 2011·Chemical Communications : Chem Comm·Chang-Bin YuYong-Gui Zhou
Jul 22, 2016·The Journal of Organic Chemistry·Qi ZhangYao Fu
Jan 20, 2017·Chemical Communications : Chem Comm·Bo SongYong-Gui Zhou
Mar 12, 2015·Chemistry : a European Journal·Yunfei CaiXiaoming Feng
Mar 20, 2010·Organic & Biomolecular Chemistry·John F BowerTimothy Gallagher
Apr 23, 2013·Chemistry : a European Journal·Agnieszka BartoszewiczBelén Martín-Matute
Jul 12, 2014·Chemical Communications : Chem Comm·Xian-Feng CaiYong-Gui Zhou
Sep 17, 2013·Angewandte Chemie·Jianzhong ChenWanbin Zhang
Nov 10, 2012·Chemical Society Reviews·Qing-An ChenYong-Gui Zhou
Sep 16, 2020·Organic & Biomolecular Chemistry·Quoc Hoang PhamStephen G Pyne
Jan 15, 2021·Chemical Communications : Chem Comm·Jingjing WangLantao Liu
Jun 18, 2010·Journal of the American Chemical Society·Duo-Sheng WangXumu Zhang
Jun 11, 2009·The Journal of Organic Chemistry·Chang-Bin YuYong-Gui Zhou

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