Enantioselective Synthesis of Fully Benzenoid Single and Double Carbohelicenes via Gold-Catalyzed Intramolecular Hydroarylation

Chemistry : a European Journal
Masakazu SatohKen Tanaka

Abstract

The enantioselective synthesis of fully benzenoid single and double carbo[6]helicenes has been achieved via the gold-catalyzed intramolecular hydroarylation. The single crystal of the racemic double carbo[6]helicene consists of unique layer structures like timbers with halving joints in the woodworking. Furthermore, the double carbo[6]helicenes exhibited relatively large CPL activities among chiral small organic molecules.

References

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Citations

May 28, 2020·Chemistry : a European Journal·Takahiro KawashimaKen Kamikawa
Jul 30, 2020·Chemistry : a European Journal·Lorenzo ArricoFrancesco Zinna
Apr 4, 2020·Journal of the American Chemical Society·Nathaniel J SchusterColin Nuckolls
Dec 15, 2020·Chemical Reviews·Christoph M HendrichA Stephen K Hashmi
Jun 12, 2019·Organic Letters·Antonio UrbanoM Carmen Carreño
Jul 22, 2021·Chemistry : a European Journal·Samuel Suárez-PantigaManuel Alcarazo

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