Enantioselective synthesis of planar-chiral phosphaferrocenes by molybdenum-catalyzed asymmetric interannular ring-closing metathesis

Journal of the American Chemical Society
Masamichi OgasawaraTamotsu Takahashi

Abstract

Enantioselective synthesis of planar-chiral phosphaferrocenes was realized for the first time by molybdenum-catalyzed asymmetric ring-closing metathesis (ARCM) in up to 99% ee, which is the first application of ARCM to induction of chirality in molecules devoid of stereogenic centers.

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Citations

Jul 7, 2020·Dalton Transactions : an International Journal of Inorganic Chemistry·Maria MazurMaria Bretner
Jul 4, 2012·Dalton Transactions : an International Journal of Inorganic Chemistry·W BuchowiczM Majchrzak
Jun 20, 2017·Dalton Transactions : an International Journal of Inorganic Chemistry·Lian DuanWenjun Zheng
Sep 26, 2013·Beilstein Journal of Organic Chemistry·Yan-Chao ShiShu-Li You
Jun 26, 2013·Dalton Transactions : an International Journal of Inorganic Chemistry·Guillaume BousrezJan Szymoniak
Apr 23, 2021·Chemical Record : an Official Publication of the Chemical Society of Japan ... [et Al.]·Masamichi Ogasawara
Aug 20, 2014·Journal of the American Chemical Society·John HartungRobert H Grubbs

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