Enhanced kinetic performance of peroxymonosulfate/ZVI system with the addition of copper ions: Reactivity, mechanism, and degradation pathways

Journal of Hazardous Materials
Wei LiHongguang Guo

Abstract

Advanced oxidation processes (AOPs) based on the bimetallic system has been demonstrated as a promising way to enhance the degradation of pollutants in the water. In this study, the degradation of Rhodamine B (RhB) in a zero-valent iron (ZVI)/ peroxymonosulfate system with Cu2+ was thoroughly investigated. RhB could be efficiently removed (99.3 %) in the optimal ZVI/PMS/Cu2+ system, while only 58.2 % of RhB could be degraded in the ZVI/PMS system. The influence of reaction parameters on the degradation of RhB was further investigated. Quenching experiments and electron paramagnetic resonance (EPR) tests revealed that various reactive oxygen species could be generated in the ternary system, of which, 1O2 and O2- were identified for the first time. The effect of various anions, NOM and different water matrix were also considered at different concentrations. A variety of byproducts and degradation pathways were identified using HPLC/MS/MS. Finally, the Quantitative Structure Activity Relationship (QSAR) method of Toxicity Estimation Software Tool (TEST) was applied to estimate the toxicity of the byproducts and the results indicated that the overall toxicity of the target was relatively reduced. This study demonstrated the potenti...Continue Reading

Citations

Aug 14, 2020·Environmental Science and Pollution Research International·Maryam Mohammadi Amini, Nezamaddin Mengelizadeh
Apr 4, 2021·International Journal of Environmental Research and Public Health·Guangfeng XiaoJiangkun Du

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