Enhanced oxidation potential of Ti/SnO2 -Cu electrode for electrochemical degradation of low-concentration ceftazidime in aqueous solution: Performance and degradation pathway

Chemosphere
Pingzhou DuanZhirong Sun

Abstract

In order to develop an efficient electrode to remove pharmaceutical and personal care products from wastewater, copper and antimony doped Ti/SnO2 electrode were prepared by thermal decomposition. Electrochemical characterization was undertaken on Ti/SnO2-Cu using cyclic voltammetry and linear sweep voltammetry, indicating an ultra-high 2.1 V of oxygen evolution potential, better stability, and superior corrosion resistance rather than traditional Ti/SnO2-Sb electrode. Competitive degradation experiments showed more efficient removal rate was achieved on Ti/SnO2-Cu electrode, which could remove more than 90% ceftazidime within 60 min. The microstructure and crystal orientation of the modified electrodes were investigated by scanning electron microscopy, which indicated that the crystal of the Ti/SnO2-Cu electrode grew in more porous and uniform condition, covered with closely arranged layers of the coating. X-ray photoelectron spectroscopy and X-ray diffractions suggested that Cu2O was successfully coated on the Ti/SnO2-Cu electrode surface. The operating parameters of electrochemical degradation process were also investigated, including current density, initial concentration, electrode distance, stirring rate and supporting ele...Continue Reading

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