Enhancement of catalytic performance in asymmetric transfer hydrogenation by microenvironment engineering of the nanocage

Chemical Communications : Chem Comm
Shiyang BaiCan Li

Abstract

Ru-TsDPEN confined in the nanocage with an amphiphilic microenvironment can be ten times more active than that with a hydrophobic one in the transfer hydrogenation of acetophenone in HCOONa-H(2)O, which is mainly due to the enhanced diffusion rates of reactants during the catalytic process.

References

Jan 16, 2003·Journal of the American Chemical Society·Anton W BosmanCraig J Hawker
Jul 1, 2004·Organic & Biomolecular Chemistry·Xiaofeng WuJianliang Xiao
Sep 16, 2004·Chemical Communications : Chem Comm·Pei Nian LiuShao Hua Wang
May 18, 2005·Accounts of Chemical Research·Xiyun Zhang, K N Houk
Aug 10, 2006·Chemical Reviews·Jiali GaoDonald G Truhlar
Feb 17, 2007·Journal of the American Chemical Society·Dennis H LeungKenneth N Raymond
Feb 28, 2007·Chemical Communications : Chem Comm·Hengquan YangCan Li
Jun 15, 2007·Chemical Communications : Chem Comm·Xiaofeng Wu, Jianliang Xiao
Jul 8, 2008·Chemistry : a European Journal·Xiaofeng WuJianliang Xiao

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Citations

Aug 31, 2016·Topics in Current Chemistry·Bogdan Štefane, Franc Požgan
May 17, 2017·Chemical Science·Ben ShiChunchang Zhao
Sep 10, 2011·Angewandte Chemie·Orion B BerrymanJulius Rebek
Jul 9, 2011·Journal of the American Chemical Society·Casey J BrownKenneth N Raymond

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