Eta2-organoazide complexes of nickel and their conversion to terminal imido complexes via dinitrogen extrusion

Journal of the American Chemical Society
Rory Waterman, Gregory L Hillhouse

Abstract

1-Adamantyl- and mesitylazide react with [(dtbpe)Ni]2(eta2-mu-C6H6) to give the eta2 organic azide adducts (dtbpe)Ni(eta2-N3R) (R = Ad, 3a; Mes, 3b) that have been isolated in good yields and crystallographically characterized. These azide adducts are intermediates in the formation of the corresponding terminal imido complexes (dtbpe)NiNR (R = Ad, 4a; Mes, 4b), undergoing intramolecular loss of dinitrogen upon mild thermolysis.

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Oct 16, 2013·Inorganic Chemistry·James A BellowStanislav Groysman
Dec 24, 2010·Journal of the American Chemical Society·Carl A LaskowskiThomas R Cundari
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