Evidence for a NiI active species in the catalytic cross-coupling of alkyl electrophiles

Journal of the American Chemical Society
Thomas J AndersonDavid A Vicic

Abstract

Addition of terpyridine to (TMEDA)Ni(CH3)2 results in the high-yield formation of (terpyridyl)NiMe (3). This NiI organometallic complex was found to be capable of transferring its methyl group to iodocyclohexane to produce methylcyclohexane in high yield. Compound 3 can also serve as an initiator for the catalytic cross-coupling of alkyl electrophiles performed under Negishi-like conditions.

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Citations

Aug 31, 2011·Accounts of Chemical Research·Shenglai Yao, Matthias Driess
Apr 28, 2011·Inorganic Chemistry·Di ZhuPeter H M Budzelaar
Jul 30, 2011·Inorganic Chemistry·James T CiszewskiDavid A Vicic
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