Evolution of aqSOA from the Air-Liquid Interfacial Photochemistry of Glyoxal and Hydroxyl Radicals

Environmental Science & Technology
Fei ZhangXiao-Ying Yu

Abstract

The effect of photochemical reaction time on glyoxal and hydrogen peroxide at the air-liquid (a-l) interface is investigated using in situ time-of-flight secondary ion mass spectrometry (ToF-SIMS) enabled by a system for analysis at the liquid vacuum interface (SALVI) microreactor. Carboxylic acids are formed mainly by reaction with hydroxyl radicals in the initial reactions. Oligomers, cluster ions, and water clusters formed due to longer photochemistry. Our results provide direct molecular evidence that water clusters are associated with proton transfer and the formation of oligomers and cluster ions at the a-l interface. The oligomer formation is facilitated by water cluster and cluster ion formation over time. Formation of higher m/z oligomers and cluster ions indicates the possibility of highly oxygenated organic components formation at the a-l interface. Furthermore, new chemical reaction pathways, such as surface organic cluster, hydration shell, and water cluster formation, are proposed based on SIMS spectral observations, and the existing understanding of glyoxal photochemistry is expanded. Our in situ findings verify that the a-l interfacial reactions are important pathways for aqueous secondary organic aerosol (aqSOA...Continue Reading

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Citations

Apr 1, 2020·Physical Chemistry Chemical Physics : PCCP·Yanjie ShenXiao-Ying Yu
Jan 22, 2021·The Journal of Physical Chemistry. a·Keaten J KappesVeronica Vaida
Apr 17, 2021·Environmental Science & Technology·Ruifeng ZhangChak K Chan
Oct 22, 2020·Environmental Science & Technology·Di HuangJincai Zhao
Dec 23, 2020·The Journal of Physical Chemistry Letters·Xiao SuiXiao-Ying Yu

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