Exceptionally long-lived luminescence from [Cu(I)(isocyanide)2(phen)]+ complexes in nanoporous crystals enables remarkable oxygen gas sensing

Journal of the American Chemical Society
Conor S Smith, Kent R Mann

Abstract

We report crystalline mixed-ligand copper complexes with phenanthroline and isocyanides with almost millesecond emission lifetimes that are efficient dioxygen sensors. The oxygen sensitivity of the prototype ([Cu(CN-xylyl)(2)(dmp)]tfpb, dmp = 2,9-dimethyl-1,10-phenanthroline; CN-xylyl = 2,6-dimethylphenylisocyanide; tfpb = tetrakis(bis-3,5-trifluoromethylphenylborate) is 38 times better than that of [Ru(phen)(3)]tfpb(2) (phen = 1,10-phenanthroline).

References

Dec 22, 1999·Analytical Chemistry·J N DemasP B Coleman
Jan 5, 2002·Journal of the American Chemical Society·Douglas G CuttellRichard A Walton
Nov 17, 2007·Journal of the American Chemical Society·Kari A McGeeKent R Mann
Mar 31, 2010·Chemistry of Materials : a Publication of the American Chemical Society·Yanqing TianDeirdre R Meldrum
Sep 22, 2010·Journal of the American Chemical Society·Conor S SmithKent R Mann

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Citations

Feb 16, 2016·Inorganic Chemistry·Gomathy ChakkaradhariIgor O Koshevoy
Jan 6, 2017·Journal of the American Chemical Society·Laura A BüldtOliver S Wenger
Jul 2, 2015·Dalton Transactions : an International Journal of Inorganic Chemistry·Gomathy ChakkaradhariIgor O Koshevoy
Apr 24, 2015·Dalton Transactions : an International Journal of Inorganic Chemistry·Michihiro NishikawaTaro Tsubomura
Jun 19, 2015·Chemical Communications : Chem Comm·Santiago Medina-RodríguezAlberto Fernández-Gutiérrez
Mar 19, 2014·Chemical Society Reviews·Xu-dong Wang, Otto S Wolfbeis
Nov 11, 2014·Dalton Transactions : an International Journal of Inorganic Chemistry·Wei-Bin YuXianwen Wei
Oct 18, 2016·Dalton Transactions : an International Journal of Inorganic Chemistry·Leandro P RavaroAndrea S S de Camargo
Jun 14, 2018·Dalton Transactions : an International Journal of Inorganic Chemistry·Zheng-Bang PanMei-Lin Ho
Aug 21, 2018·Dalton Transactions : an International Journal of Inorganic Chemistry·Kassio P S ZanoniAndrea S S de Camargo
Oct 8, 2016·Advanced Materials·Hai-Ying JiangJincai Zhao
Feb 18, 2017·Dalton Transactions : an International Journal of Inorganic Chemistry·Elnaz HobbollahiUwe Monkowius
Sep 12, 2017·Chemistry : a European Journal·Christopher B Larsen, Oliver S Wenger
Oct 31, 2017·Chemphyschem : a European Journal of Chemical Physics and Physical Chemistry·Hartmut YersinAlfiya F Suleymanova
Feb 8, 2019·Dalton Transactions : an International Journal of Inorganic Chemistry·Marsel Z ShafikovHartmut Yersin
Sep 26, 2017·Dalton Transactions : an International Journal of Inorganic Chemistry·Jing-Lin ChenWai-Yeung Wong
Nov 4, 2016·Chemical Society Reviews·Yong-Jun YuanZhi-Gang Zou
Dec 12, 2012·Bioanalytical Reviews·Michela QuarantaIngo Klimant
Sep 30, 2016·Inorganic Chemistry·Sofia GarakyaraghiFelix N Castellano
Jan 23, 2020·Inorganic Chemistry·Alexandra A ShmakovaMaxim N Sokolov
Oct 12, 2021·Inorganic Chemistry·Alexander C MarwitzKarah E Knope
Nov 18, 2021·Dalton Transactions : an International Journal of Inorganic Chemistry·Gregory D SuttonThomas S Teets

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