Experimental and Theoretical Evidence for an Agostic Interaction in a Gold(III) Complex

Angewandte Chemie
Feriel RekhroukhDidier Bourissou

Abstract

The first agostic interaction in a gold complex is described. The presence of a bonding C-H⋅⋅⋅Au interaction in a cationic "tricoordinate" gold(III) complex was suggested by DFT calculations and was subsequently confirmed by NMR spectroscopy at low temperature. The agostic interaction was analyzed computationally using NBO and QTAIM analyses (NBO=natural bond orbital; QTAIM=quantum theory of atoms in molecules).

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Citations

Aug 18, 2016·Journal of the American Chemical Society·Feriel RekhroukhDidier Bourissou
Feb 6, 2017·Dalton Transactions : an International Journal of Inorganic Chemistry·P I da S MaiaU Abram
Jul 7, 2017·Dalton Transactions : an International Journal of Inorganic Chemistry·Guillermo Moreno-AlcántarHugo Torrens
Jun 2, 2018·Dalton Transactions : an International Journal of Inorganic Chemistry·Charlie BlonsDidier Bourissou
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Aug 7, 2017·Angewandte Chemie·Anthony PujolNicolas Mézailles
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Jan 3, 2019·Angewandte Chemie·Michal StrakaLubomír Rulíšek
Sep 20, 2017·Nature Communications·Md Abu BakarKatsuaki Konishi
Apr 4, 2019·Angewandte Chemie·Hubert Schmidbaur
Apr 24, 2019·Dalton Transactions : an International Journal of Inorganic Chemistry·Alice JohnsonAndrew S Weller
Nov 7, 2019·Angewandte Chemie·Jessica RodriguezDidier Bourissou
Sep 16, 2020·Dalton Transactions : an International Journal of Inorganic Chemistry·Maryne DuvalDidier Bourissou
Sep 11, 2019·Physical Chemistry Chemical Physics : PCCP·Yann Cornaton, Jean-Pierre Djukic
Dec 21, 2018·Proceedings of the National Academy of Sciences of the United States of America·Mathilde RigouletDidier Bourissou
Mar 27, 2020·Dalton Transactions : an International Journal of Inorganic Chemistry·Laura Estévez
Jul 1, 2017·Chemical Science·Feriel RekhroukhDidier Bourissou
Nov 21, 2019·Inorganic Chemistry·Emanuel HupfJens Beckmann
Dec 15, 2020·Chemical Reviews·Christoph M HendrichA Stephen K Hashmi
Jul 28, 2021·Angewandte Chemie·Heidar DarmandehViktoria H Gessner
Nov 13, 2021·Dalton Transactions : an International Journal of Inorganic Chemistry·Basvaraj S KoteMaravanji S Balakrishna

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