PMID: 11327987May 1, 2001Paper

Experimental evidence for a kinetic transition in reversible reactions

Physical Review Letters
K M SolntsevNoam Agmon

Abstract

We provide a first experimental verification of a theoretical prediction of a kinetic transition in a reversible binding reaction, AB right harpoon over left harpoon A+B, driven by the difference in effective lifetimes of the bound and the unbound states. We consider the kinetics of excited-state proton transfer to solvent from a photoacid whose conjugate anionic base possesses an extremely short unbound anion lifetime. Its solvent variation relative to the overall dissociation rate coefficient induces a transition in the kinetics, from power law to exponential.

References

Apr 1, 1997·Biophysical Journal·N Agmon, A L Edelstein

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Citations

Feb 19, 2009·Physical Chemistry Chemical Physics : PCCP·Gregor JungAlexander Schmitt
Jun 24, 2010·The Journal of Chemical Physics·Kihyun ParkHyojoon Kim
Feb 2, 2011·The Journal of Chemical Physics·Jiang-Xing Chen, Raymond Kapral
Feb 26, 2009·The Journal of Chemical Physics·Soohyung Park, Noam Agmon
May 17, 2014·The Journal of Chemical Physics·Alexander B Doktorov, Alexey A Kipriyanov
Jan 10, 2013·Annual Review of Physical Chemistry·Arnulf RosspeintnerEric Vauthey
Nov 21, 2012·The Journal of Chemical Physics·Svetlana S Khokhlova, Noam Agmon
Jun 17, 2008·Chemistry, an Asian Journal·Soohyung Park, Kook Joe Shin
Feb 25, 2014·Physical Chemistry Chemical Physics : PCCP·Carlos Echeverria, Raymond Kapral
Oct 24, 2013·Physical Chemistry Chemical Physics : PCCP·Christian SpiesGregor Jung
Nov 3, 2016·Chemphyschem : a European Journal of Chemical Physics and Physical Chemistry·Chun-Gang MinYan-Qin Zhu
Jul 15, 2006·The Journal of Physical Chemistry. a·Noam Agmon
Mar 7, 2009·The Journal of Physical Chemistry. a·Shigeo KanekoSeiji Tobita
Nov 12, 2010·The Journal of Physical Chemistry. B·Horacio BottiRafael Radi
Dec 14, 2016·Chemical Reviews·Tatu KumpulainenEric Vauthey
Dec 1, 2007·The Journal of Physical Chemistry. B·Soohyung Park, Kook Joe Shin
Jul 21, 2006·The Journal of Physical Chemistry. B·Han Jung ParkDu-Jeon Jang
Jun 28, 2006·The Journal of Physical Chemistry. B·Oh-Hoon KwonDu-Jeon Jang
Jan 16, 2002·Accounts of Chemical Research·Laren M Tolbert, Kyril M Solntsev

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