Exploitation of knowledge databases in the synthesis of zinc(II) malonates with photo-sensitive and photo-insensitive N ,N '-containing linkers

IUCrJ
Ekaterina N Zorina-TikhonovaAnna V Vologzhanina

Abstract

Photoinitiated solid-state reactions are known to affect the physical properties of coordination polymers, such as fluorescence and sorption behaviour, and also afford extraordinary architectures (e.g. three-periodic structures with polyorganic ligands). However, the construction of novel photo-sensitive coordination polymers requires an understanding of the factors which govern the mutual disposition of reactive fragments. A series of zinc(II) malonate complexes with 1,2-bis(pyridin-4-yl)ethylene and its photo-insensitive analogues has been synthesized for the purpose of systematic analysis of their underlying nets and mutual disposition of N-donor ligands. The application of a big data-set analysis for the prediction of a variety of possible complex compositions, coordination environments and networks for a four-component system has been demonstrated for the first time. Seven of the nine compounds possess one of the highly probable topologies for their underlying nets; in addition, two novel closely related four-coordinated networks were obtained. Complexes containing 1,2-bis(pyridin-4-yl)ethylene and 1,2-bis(pyridin-4-yl)ethane form isoreticular compounds more readily than those with 4,4'-bipyridine and 1,2-bis(pyridin-4-yl)...Continue Reading

References

Jun 13, 2003·Nature·Omar M YaghiJaheon Kim
Jul 30, 2004·Journal of the American Chemical Society·Giannis S PapaefstathiouLeonard R MacGillivray
Apr 29, 2008·Chemistry : a European Journal·Abdul Malik Puthan Peedikakkal, Jagadese J Vittal
Oct 7, 2008·Accounts of Chemical Research·Michael O'KeeffeOmar M Yaghi
Jan 22, 2009·Acta Crystallographica. Section B, Structural Science·Viktor N SerezhkinMikhail Yu Antipin
Jun 3, 2010·Chemical Communications : Chem Comm·Ivan G GeorgievLeonard R Macgillivray
Aug 25, 2011·Chemical Society Reviews·Hubert Schmidbaur, Annette Schier
Mar 28, 2012·Chemical Communications : Chem Comm·Hiroshi SatoSusumu Kitagawa
Aug 31, 2013·Science·Hiroyasu FurukawaOmar M Yaghi
Nov 21, 2013·Chemical Communications : Chem Comm·Anjana ChanthapallyJagadese J Vittal
Jan 3, 2014·Angewandte Chemie·Colin R Groom, Frank H Allen
Oct 28, 2015·Chemical Reviews·Eugeny V AlexandrovEugenia V Peresypkina
Apr 7, 2016·Acta Crystallographica Section B, Structural Science, Crystal Engineering and Materials·Colin R GroomSuzanna C Ward

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Citations

Nov 27, 2018·Chemical Communications : Chem Comm·Alexander D VolodinAnna V Vologzhanina

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Methods Mentioned

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X-ray
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Systre
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