Exploring Mn-O bonding in the context of an electronically flexible secondary coordination sphere: synthesis of a Mn(III)-oxo

Chemical Communications : Chem Comm
Yun Ji ParkAlison R Fout

Abstract

Complexes containing manganese-oxygen bonds have been implicated in a variety of biological and synthetic processes. Herein, we describe the synthesis of a family of stable, high-spin trigonal bipyramidal manganese complexes of the electronically flexible ligand tris(5-cyclohexylimino-pyrrol-2-ylmethyl)amine [H3N(pi(Cy))3] featuring apical water, hydroxyl, and oxo ligands. Terminal Mn(III)-O complexes are rare and the formation of this species was achieved from a variety of reagents including O2, PhIO and NO2(-). Described herein is the preparation, structural and electronic properties of these manganese complexes.

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Citations

May 15, 2015·Dalton Transactions : an International Journal of Inorganic Chemistry·Ellen M MatsonAlison R Fout
Nov 16, 2016·Science·Courtney L FordAlison R Fout
Aug 30, 2017·Dalton Transactions : an International Journal of Inorganic Chemistry·Sergiu ShovaVladimir B Arion
Dec 15, 2020·Chemical Society Reviews·Shunichi FukuzumiWonwoo Nam
Oct 10, 2018·Inorganic Chemistry·Victoria F OswaldA S Borovik
Aug 8, 2019·Inorganic Chemistry·Evan J GardnerTimothy H Warren
May 16, 2019·Journal of the American Chemical Society·Christopher J Reed, Theodor Agapie
Sep 9, 2021·Journal of the American Chemical Society·Adedamola A OpaladeTimothy A Jackson

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