Exquisite sensitivity of the ligand field to solvation and donor polarisability in coordinatively saturated lanthanide complexes

Chemical Communications : Chem Comm
Kevin MasonDavid Parker

Abstract

Crystallographic, emission and NMR studies of a series of C3-symmetric, nine-coordinate substituted pyridyl triazacyclononane Yb(iii) and Eu(iii) complexes reveal the impact of local solvation and ligand dipolar polarisability on ligand field strength, leading to dramatic variations in pseudocontact NMR shifts and emission spectral profiles, giving new guidance for responsive NMR and spectral probe design.

References

Dec 21, 2010·Journal of Magnetic Resonance·H J HogbenIlya Kuprov
Dec 18, 2013·Chemical Reviews·Marie C HeffernThomas J Meade
Feb 24, 2016·Dalton Transactions : an International Journal of Inorganic Chemistry·Octavia A BlackburnSergey Shuvaev
Mar 16, 2016·Inorganic Chemistry·Goretti CastroLaura Valencia
Sep 9, 2017·Journal of the American Chemical Society·Michele VonciNicholas F Chilton

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Citations

Aug 31, 2018·Chemistry : a European Journal·Adeline W J PohDavid Parker
Mar 8, 2019·Dalton Transactions : an International Journal of Inorganic Chemistry·Zihan ZhangPengfei Yan
May 23, 2019·Dalton Transactions : an International Journal of Inorganic Chemistry·Elizaveta A SuturinaDavid Parker
Jan 11, 2020·Chemistry : a European Journal·Loic Joanny CharbonnièreMauro Botta
May 30, 2020·Physical Chemistry Chemical Physics : PCCP·Patrick R NawrockiThomas Just Sørensen
Nov 1, 2018·Dalton Transactions : an International Journal of Inorganic Chemistry·Laura B JenningsDavid Parker
Apr 11, 2020·RSC Advances·Michael A CaldwellThomas J Meade
Mar 11, 2021·Dalton Transactions : an International Journal of Inorganic Chemistry·Daniel KovacsK Eszter Borbas
May 6, 2021·Inorganic Chemistry·Nicolaj KofodThomas Just Sørensen
Mar 6, 2019·Inorganic Chemistry·David Esteban-GómezCarlos Platas-Iglesias
Jan 25, 2020·The Journal of Physical Chemistry. a·Aurora Rodríguez-RodríguezCarlos Platas-Iglesias
Nov 7, 2019·Inorganic Chemistry·Lea Gundorff Nielsen, Thomas Just Sørensen

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Methods Mentioned

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