PMID: 26328355Sep 4, 2015Paper

Fabrication of Mesoporous Carbon Tube and Foam: Application as Supports in Enantio-Selective Separation of Optically Pure Amino Acid from Racemates

Journal of Nanoscience and Nanotechnology
Hoon-Gi JeonGeon-Joong Kim

Abstract

The mesoporous monolithic carbon (MMC) foams and carbon tubes were newly fabricated in cm-scale using the mixture of triblock copolymers and phenol/HCHO resin precursors. The regular mesoporosity were formed in the body of MMC foam and carbon fibers. In this work, the organic phases containing chiral ARCA adsorbent and a phase transfer catalyst were coated on the surfaces of mesoporous carbon support, and this ARCA/carbon mixture was adopted for the enantioselective separation of amino acid in the circulation system. (S)-ARCA coated MMC support showed high selcetivity up to 90% for the separation of D-type phenylalanine, serine and tryptophan from racemic mixtures.

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