Fabrication of spent FCC catalyst composites by loaded V2 O5 and TiO2 and their comparative photocatalytic activities

Scientific Reports
Jiasheng Xu, Te Zhang

Abstract

The spent fluid catalytic cracking catalyst (FCC) has been loaded with different content of V2O5 and TiO2 through a modified-impregnation method. X-ray Diffraction (XRD), ultraviolet-visible spectrophotometry (UV-Vis), Scanning Electron Microscope (SEM), and Fourier Transform Infrared spectroscopy (FT-IR) are used to characterize the structure and morphology of these samples. Their photocatalytic activity was evaluated by degradation of methylene blue (MB) solution under 300 W Xenon lamp irradiation. The interplanar spacing of the zeolite Y (111) plane is affected by the amount of the loaded V2O5 on spent FCC catalyst. The (111) plane of spent FCC catalyst loaded with V2O5 and TiO2 sample is 1.404 nm, which is higher than that of the zeolite Y (1.395 nm). The amount of adsorption of MB and the photocatalytic activity for the degradation increased with increasing the interplanar spacing of the (111) plane of sample. We fabricated of spent FCC catalyst composites by loaded V2O5 and TiO2, which effectively solved the spent FCC catalyst disposal problem. The efficiency of the developed sample provides a potentially economical way of degrading MB.

References

Nov 20, 2001·Nature·M Grätzel
Jul 21, 2015·Waste Management·Ata AkcilAysenur Tuncuk
Sep 19, 2015·Chemical Society Reviews·E T C Vogt, B M Weckhuysen

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