Facile and reversible double dearomatization of pyridines in non-phosphine MnI complexes with N,S-donor pyridinophane ligand

Chemical Communications : Chem Comm
Abir SarbajnaJulia R Khusnutdinova

Abstract

Single and double dearomatization of pyridine rings was observed in MnI complexes with an N2S2 pyridinophane ligand via deprotonation of one or two CH2 arms, respectively. In contrast to other N,S-donor pincer-like systems, the dearomatized (N2S2)Mn species were found to be stable, with the dearomatization being reversible.

References

Oct 2, 2003·Chemical Society Reviews·David J Evans, Christopher J Pickett
Feb 1, 2008·Angewandte Chemie·Hansjörg Grützmacher
Jul 12, 2011·Accounts of Chemical Research·Chidambaram Gunanathan, David Milstein
Jan 29, 2013·Angewandte Chemie·Denis SpasyukDmitry G Gusev
Nov 15, 2014·Chemical Reviews·Chidambaram Gunanathan, David Milstein
Mar 25, 2015·Angewandte Chemie·Barry M Trost, Meera Rao
Oct 6, 2015·Angewandte Chemie·Julia R Khusnutdinova, David Milstein
May 25, 2016·Journal of the American Chemical Society·Saravanakumar ElangovanMatthias Beller
Oct 1, 2016·Angewandte Chemie·Saravanakumar ElangovanMatthias Beller
Apr 7, 2017·Chemistry : a European Journal·Pim PuylaertJohannes G de Vries
Apr 21, 2017·Angewandte Chemie·Magnus B WidegrenMatthew L Clarke
Apr 22, 2017·Angewandte Chemie·Robbert van PuttenEvgeny A Pidko
Jun 5, 2018·Accounts of Chemical Research·Nikolaus Gorgas, Karl Kirchner

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Methods Mentioned

BETA
X-ray
NMR

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