Facile Approach to Graft Ionic Liquid into MOF for Improving the Efficiency of CO2 Chemical Fixation

ACS Applied Materials & Interfaces
Yuxiu SunShengqian Ma

Abstract

This work describes a facile approach to modify metal-organic frameworks (MOFs) with ionic liquids (ILs), rendering them as useful heterogeneous catalysts for CO2 chemical fixation. An amino-functionalized imidazolium-based ionic liquid is firmly grafted into the porous MOF, MIL-101-SO3H by the acid-base attraction between positively charged ammonium groups on the IL and negatively charged sulfonate groups from the MOF. Analyses by Fourier transform infrared spectroscopy, X-ray photoelectron spectroscopy, 1H NMR, and N2 sorption experiments reveal the MOF-supported ionic liquid (denoted as IL@MOF) material remains intact while functioning as a recyclable heterogeneous catalyst that can efficiently convert CO2 and epichlorohydrin into chloropropene carbonate without the addition of a cocatalyst.

References

Feb 7, 2002·Journal of the American Chemical Society·Eleanor D BatesJames H Davis
Oct 10, 2002·Chemical Reviews·Jairton DupontPaulo A Z Suarez
Dec 23, 2004·Accounts of Chemical Research·Donald J DarensbourgDamon R Billodeaux
Oct 20, 2010·Angewandte Chemie·Antonello DecortesArjan W Kleij
Dec 30, 2011·Chemical Reviews·Kenji SumidaJeffrey R Long
Jan 7, 2014·Chemistry : a European Journal·Nazmul Abedin KhanSung Hwa Jhung
Oct 21, 2016·Small·Hongming HeShengqian Ma
Apr 26, 2017·Topics in Current Chemistry·Hendrik BüttnerThomas Werner

❮ Previous
Next ❯

Citations

May 30, 2019·Chemical Communications : Chem Comm·Yanyan WangBuxing Han
Sep 12, 2019·Chemistry, an Asian Journal·Anand Yadav, Prakash Kanoo
Jan 7, 2020·Topics in Current Chemistry·Ying ShiBin Zhao
Jul 9, 2020·Dalton Transactions : an International Journal of Inorganic Chemistry·Feng Guo, Xiuling Zhang
Aug 19, 2020·Dalton Transactions : an International Journal of Inorganic Chemistry·Shengxian ChengZhengtao Xu
Sep 24, 2020·Membranes·Sofia M MorozovaAlexander S Shaplov
Jul 3, 2021·Molecules : a Journal of Synthetic Chemistry and Natural Product Chemistry·Reem ShomalSulaiman Al-Zuhair
Jan 29, 2022·Inorganic Chemistry·Chen-Yen TsaiWan-Ling Liu

❮ Previous
Next ❯

Related Concepts

Trending Feeds

COVID-19

Coronaviruses encompass a large family of viruses that cause the common cold as well as more serious diseases, such as the ongoing outbreak of coronavirus disease 2019 (COVID-19; formally known as 2019-nCoV). Coronaviruses can spread from animals to humans; symptoms include fever, cough, shortness of breath, and breathing difficulties; in more severe cases, infection can lead to death. This feed covers recent research on COVID-19.

Blastomycosis

Blastomycosis fungal infections spread through inhaling Blastomyces dermatitidis spores. Discover the latest research on blastomycosis fungal infections here.

Nuclear Pore Complex in ALS/FTD

Alterations in nucleocytoplasmic transport, controlled by the nuclear pore complex, may be involved in the pathomechanism underlying multiple neurodegenerative diseases including Amyotrophic Lateral Sclerosis and Frontotemporal Dementia. Here is the latest research on the nuclear pore complex in ALS and FTD.

Applications of Molecular Barcoding

The concept of molecular barcoding is that each original DNA or RNA molecule is attached to a unique sequence barcode. Sequence reads having different barcodes represent different original molecules, while sequence reads having the same barcode are results of PCR duplication from one original molecule. Discover the latest research on molecular barcoding here.

Chronic Fatigue Syndrome

Chronic fatigue syndrome is a disease characterized by unexplained disabling fatigue; the pathology of which is incompletely understood. Discover the latest research on chronic fatigue syndrome here.

Evolution of Pluripotency

Pluripotency refers to the ability of a cell to develop into three primary germ cell layers of the embryo. This feed focuses on the mechanisms that underlie the evolution of pluripotency. Here is the latest research.

Position Effect Variegation

Position Effect Variagation occurs when a gene is inactivated due to its positioning near heterochromatic regions within a chromosome. Discover the latest research on Position Effect Variagation here.

STING Receptor Agonists

Stimulator of IFN genes (STING) are a group of transmembrane proteins that are involved in the induction of type I interferon that is important in the innate immune response. The stimulation of STING has been an active area of research in the treatment of cancer and infectious diseases. Here is the latest research on STING receptor agonists.

Microbicide

Microbicides are products that can be applied to vaginal or rectal mucosal surfaces with the goal of preventing, or at least significantly reducing, the transmission of sexually transmitted infections. Here is the latest research on microbicides.