Facile Construction of Structurally Defined Porous Membranes from Supramolecular Hexakistriphenylamine Metallacycles through Electropolymerization

Chemistry : a European Journal
Hai-Bo YangYu-Wu Zhong

Abstract

The construction of well-controlled porous materials is very challenging. Herein, we report the successful preparation of structurally defined porous membranes based on hexakistriphenylamine metallacycles through electropolymerization. The newly designed porous materials were characterized by the typical cyclic voltammograms, XPS, SEM, and TEM investigations. Further investigations revealed that the metallacycle-based polymer films displayed a good size-selective molecular-sieving behavior.

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Citations

Apr 19, 2018·Frontiers in Chemistry·Khushwant SinghNeeladri Das
Feb 23, 2019·Accounts of Chemical Research·Yan SunPeter J Stang
Oct 6, 2018·Journal of the American Chemical Society·Lei WangXiaopeng Li

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