Fe(II) spin-crossover phenomenon in the pentadecanuclear {Fe9[Re(CN)8]6} spherical cluster

Angewandte Chemie
Szymon ChorazyShin-Ichi Ohkoshi

Abstract

The self-assembly of iron(II) ions with rare octacyanidorhenate(V) metalloligands in a methanolic solution results in the formation of a nanometric pentadecanuclear {Fe(II) 9 [Re(V) (CN)8 ]6 (MeOH)24 }⋅10 MeOH (1) molecule with a six-capped body-centered cubic topology. The cluster demonstrates a thermally-induced spin-crossover phase transition at T1/2 =195 K which occurs selectively for a single Fe(II)  ion embedded in the center of a cluster core.

References

Feb 27, 2003·Journal of the American Chemical Society·Miriam V Bennett, Jeffrey R Long
Nov 24, 2004·Nature Materials·Shin-Ichi OhkoshiKazuhito Hashimoto
Nov 26, 2004·Journal of the American Chemical Society·Serena MargadonnaAndrew N Fitch
Mar 18, 2005·Journal of the American Chemical Society·You SongXiao-Zeng You
Jun 16, 2005·Journal of the American Chemical Society·Wataru KosakaShin-Ichi Ohkoshi
Aug 18, 2005·Journal of the American Chemical Society·Tomohiro NuidaShin-Ichi Ohkoshi
Jun 6, 2006·Dalton Transactions : an International Journal of Inorganic Chemistry·Danna E FreedmanJeffrey R Long
Jun 22, 2006·Journal of the American Chemical Society·Dionisis PapanikolaouKosmas Prassides
Mar 8, 2007·Angewandte Chemie·Shin-ichi OhkoshiKazuhito Hashimoto
Oct 13, 2007·Journal of the American Chemical Society·Wakako KanekoSusumu Kitagawa
Aug 20, 2008·Nature Materials·Cyrille TrainMichel Verdaguer
Dec 25, 2008·Angewandte Chemie·Martin B DuriskaStuart R Batten
May 8, 2009·Chemical Society Reviews·Rashmi Bagai, George Christou
Nov 4, 2009·Journal of the American Chemical Society·Cyrille TrainShin-ichi Ohkoshi
Jan 22, 2010·The Journal of Physical Chemistry. B·Christian ChongFrançois Varret
Feb 18, 2010·Dalton Transactions : an International Journal of Inorganic Chemistry·Roman BocaFranz Renz
Mar 30, 2010·Journal of the American Chemical Society·Eugenio CoronadoMassimiliano Cavallini
Jan 7, 2011·Nature·George M Whitesides, John Deutch
Feb 8, 2011·Chemical Society Reviews·Pierre Dechambenoit, Jeffrey R Long
Mar 29, 2011·Angewandte Chemie·Yan-Zhen ZhengRichard E P Winpenny
Apr 1, 2011·Chemical Society Reviews·Cyrille TrainMichel Verdaguer
Apr 12, 2011·Chemical Society Reviews·Joel S Miller
Jun 24, 2011·Nature Chemistry·Shin-Ichi OhkoshiHiroko Tokoro
Jul 7, 2012·Angewandte Chemie·Emilio PardoMichel Verdaguer
Aug 8, 2012·Accounts of Chemical Research·Shin-ichi Ohkoshi, Hiroko Tokoro
Mar 19, 2013·Beilstein Journal of Organic Chemistry·Philipp GütlichYann Garcia
Jun 19, 2013·Chemical Communications : Chem Comm·Szymon ChorazyBarbara Sieklucka
Feb 21, 2014·Chemical Communications : Chem Comm·Szymon ChorazyBarbara Sieklucka
May 17, 2014·Nature Communications·Takuto MatsumotoHiroki Oshio
Oct 10, 2014·Journal of the American Chemical Society·Evangelia S KoumousiRodolphe Clérac

❮ Previous
Next ❯

Citations

May 6, 2016·Inorganic Chemistry·Zheng YanMing-Liang Tong
Mar 23, 2017·Inorganic Chemistry·Mirosław ArczyńskiDawid Pinkowicz
Nov 9, 2017·Molecules : a Journal of Synthetic Chemistry and Natural Product Chemistry·Szymon ChorazyBarbara Sieklucka
Aug 12, 2016·Dalton Transactions : an International Journal of Inorganic Chemistry·Daniel UnruhFranz Renz
Nov 2, 2016·Dalton Transactions : an International Journal of Inorganic Chemistry·Chunyang ZhengDongfeng Li
Mar 21, 2020·Dalton Transactions : an International Journal of Inorganic Chemistry·Hui-Shu LuZhi-Guo Gu
Jul 21, 2020·Chemical Society Reviews·Szymon ChorazyBarbara Sieklucka
May 19, 2017·Dalton Transactions : an International Journal of Inorganic Chemistry·Szymon ChorazyRobert Podgajny
Aug 20, 2020·Chemistry : a European Journal·Verónica Jornet-MolláFrancisco M Romero
Nov 19, 2020·Dalton Transactions : an International Journal of Inorganic Chemistry·Jedrzej KobylarczykRobert Podgajny
Nov 7, 2019·Journal of the American Chemical Society·Izar Capel BerdiellMalcolm A Halcrow

❮ Previous
Next ❯

Related Concepts

Trending Feeds

COVID-19

Coronaviruses encompass a large family of viruses that cause the common cold as well as more serious diseases, such as the ongoing outbreak of coronavirus disease 2019 (COVID-19; formally known as 2019-nCoV). Coronaviruses can spread from animals to humans; symptoms include fever, cough, shortness of breath, and breathing difficulties; in more severe cases, infection can lead to death. This feed covers recent research on COVID-19.

Blastomycosis

Blastomycosis fungal infections spread through inhaling Blastomyces dermatitidis spores. Discover the latest research on blastomycosis fungal infections here.

Nuclear Pore Complex in ALS/FTD

Alterations in nucleocytoplasmic transport, controlled by the nuclear pore complex, may be involved in the pathomechanism underlying multiple neurodegenerative diseases including Amyotrophic Lateral Sclerosis and Frontotemporal Dementia. Here is the latest research on the nuclear pore complex in ALS and FTD.

Applications of Molecular Barcoding

The concept of molecular barcoding is that each original DNA or RNA molecule is attached to a unique sequence barcode. Sequence reads having different barcodes represent different original molecules, while sequence reads having the same barcode are results of PCR duplication from one original molecule. Discover the latest research on molecular barcoding here.

Chronic Fatigue Syndrome

Chronic fatigue syndrome is a disease characterized by unexplained disabling fatigue; the pathology of which is incompletely understood. Discover the latest research on chronic fatigue syndrome here.

Evolution of Pluripotency

Pluripotency refers to the ability of a cell to develop into three primary germ cell layers of the embryo. This feed focuses on the mechanisms that underlie the evolution of pluripotency. Here is the latest research.

Position Effect Variegation

Position Effect Variagation occurs when a gene is inactivated due to its positioning near heterochromatic regions within a chromosome. Discover the latest research on Position Effect Variagation here.

STING Receptor Agonists

Stimulator of IFN genes (STING) are a group of transmembrane proteins that are involved in the induction of type I interferon that is important in the innate immune response. The stimulation of STING has been an active area of research in the treatment of cancer and infectious diseases. Here is the latest research on STING receptor agonists.

Microbicide

Microbicides are products that can be applied to vaginal or rectal mucosal surfaces with the goal of preventing, or at least significantly reducing, the transmission of sexually transmitted infections. Here is the latest research on microbicides.

Related Papers

Journal of the American Chemical Society
Wataru KosakaShin-Ichi Ohkoshi
Journal of the American Chemical Society
Eugenio CoronadoIñigo J Vitórica-Yrezábal
Advances in Experimental Medicine and Biology
P M HarrisonS J Yewdall
© 2022 Meta ULC. All rights reserved