Fluorocarbene, fluoroolefin, and fluorocarbyne complexes of Rh

Chemical Science
Christopher J PellOleg V Ozerov

Abstract

The manuscript reports the synthesis, characterization, and analysis of electronic structure in a series of complexes of small perfluorocarbon ligands with the (PNP)Rh fragment (where PNP is a diarylamido/bis(phosphine) pincer ligand). Reactions of (PNP)Rh(TBE) as the source of (PNP)Rh with CHF3 and C2HF5 produced perfluoroalkylidene complexes (PNP)Rh 0000000000000000000000000000000000 0000000000000000000000000000000000 0000000000000000000000000000000000 0000000000000000000000000000000000 0000000000000000000000000000000000 0000000000000000000000000000000000 0000000000000000000000000000000000 0000000000000000000000000000000000 0000000000000000000000000000000000 0000000000000000000000000000000000 0000000000000000000000000000000000 0000000000000000000000000000000000 0000000000000000000000000000000000 0000000000000000000000000000000000 0000000000000000000000000000000000 1111111111111111111111111111111111 1111111111111111111111111111111111 0000000000000000000000000000000000 0000000000000000000000000000000000 0000000000000000000000000000000000 0000000000000000000000000000000000 1111111111111111111111111111111111 1111111111111111111111111111111111 0000000000000000000000000000000000 0000000000000000000000000000000000 000000000000000000...Continue Reading

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Citations

Aug 12, 2017·Chemistry : a European Journal·Alexander V ZabulaEric J Schelter
Jun 29, 2018·Angewandte Chemie·Takeshi FujitaJunji Ichikawa
Jan 19, 2019·Chemical Communications : Chem Comm·Harrison J Barnett, Anthony F Hill
May 28, 2019·Angewandte Chemie·Shintaro TakahashiTsuyoshi Kato
Jul 25, 2019·Chemical Communications : Chem Comm·Meaghan M Deegan, Jonas C Peters
Nov 23, 2019·Dalton Transactions : an International Journal of Inorganic Chemistry·Lewis M HallJohn M Slattery
Apr 19, 2019·Angewandte Chemie·Alexander G TskhovrebovAlois Fürstner
May 26, 2017·Angewandte Chemie·Lewis M HallJohn M Slattery
Oct 18, 2020·Chemistry : a European Journal·Annie L ColebatchChee S Onn
Sep 21, 2018·Journal of the American Chemical Society·Furong LinSimon Duttwyler
Aug 12, 2017·Journal of the American Chemical Society·Devin M FergusonMelanie S Sanford
Nov 20, 2021·Chemical Reviews·Anders Reinholdt, Jesper Bendix

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Methods Mentioned

BETA
NMR
X-ray

Software Mentioned

Jaguar

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