Foldamer-based helicate displaying reversible switching between two distinct conformers

Chemical Communications : Chem Comm
Hae-Geun JeonKyu-Sung Jeong

Abstract

A new double-stranded dinuclear helicate that displays conformational switching in response to temperature was prepared by self-assembly of an aromatic helical foldamer and dichloropalladium(ii). The relative populations of the two helicate conformers, syn-anti and syn-syn, were demonstrated to be reversibly modulated through temperature control.

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Citations

Mar 14, 2020·Chemistry : a European Journal·Yoshinao ShinozakiHitoshi Tamiaki
Aug 28, 2019·Chemical Communications : Chem Comm·Kai ZhangQuan Gan
Jul 28, 2020·Molecules : a Journal of Synthetic Chemistry and Natural Product Chemistry·Samuele Rinaldi

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Methods Mentioned

BETA
X-ray
NMR
2D-exchange

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