Formation and cleavage of C-H, C-C, and C-O bonds of ortho-methyl-substituted anisoles by late transition metals

Journal of the American Chemical Society
Patricia LaraErnesto Carmona

Abstract

2,6-Dimethyl-substituted anisoles can be converted into the corresponding 2-ethyl-6-methylphenols in a several-step reaction mediated by a TpMe2Ir(III) complex; use of the 13C-enriched anisoles, ArO13CH3, shows that the 13C label distributes across the two ethyl sites with a preference for the terminal position.

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Citations

Oct 18, 2016·Dalton Transactions : an International Journal of Inorganic Chemistry·Manuel A OrtuñoRobin N Perutz
Feb 13, 2013·Chemistry : a European Journal·Crispín CristóbalErnesto Carmona
May 31, 2007·Chemistry : a European Journal·Walter BarattaPierluigi Rigo
Feb 20, 2014·Chemical Communications : Chem Comm·Naseralla A JasimAdrian C Whitwood
Nov 17, 2016·Chemical Society Reviews·Addison N Desnoyer, Jennifer A Love
Oct 16, 2009·Journal of the American Chemical Society·Jongwook ChoiAlan S Goldman
Feb 2, 2010·Accounts of Chemical Research·Salvador ConejeroErnesto Carmona
Mar 19, 2015·Journal of the American Chemical Society·Ángela VivancosEleuterio Álvarez
Jun 6, 2007·Inorganic Chemistry·Chunhui HuangWei Huang

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