Four tetrairidium carbonyl clusters linked by six diphosphino ligands: synthesis and X-ray structure of [{Ir(4)(CO)(9)}(4)(dppmb)(6)] (dppmb = 1,4-bis(diphenylphosphinomethyl)benzene

Dalton Transactions : an International Journal of Inorganic Chemistry
Giulia PeliLuigi Garlaschelli

Abstract

Tetrairidium carbonyl clusters are potentially useful connectors for multidimensional functionalized frameworks with organic bis-phosphines as linkers. The reaction of Ir(4)(CO)(12) and 1,4-bis(diphenylphosphinomethyl)benzene produces an oligomeric cyclic structure, made of 4 connectors and 6 linkers, a possible intermediate in the formation of three dimensional networks.

References

Nov 17, 2001·Chemical Reviews·J C GabrielP Batail
Dec 17, 2005·Dalton Transactions : an International Journal of Inorganic Chemistry·Viktor MobergEbbe Nordlander
Jul 10, 2009·Chemical Society Reviews·Stuart L James

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Citations

Apr 5, 2011·Dalton Transactions : an International Journal of Inorganic Chemistry·Roberto Della PergolaPiero Zanello
Dec 22, 2011·Dalton Transactions : an International Journal of Inorganic Chemistry·Alexander OkrutAlexander Katz

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