Fractionation of oil sands-process affected water using pH-dependent extractions: a study of dissociation constants for naphthenic acids species

Chemosphere
Rongfu HuangMohamed Gamal El-Din

Abstract

The fractionation of oil sands process-affected water (OSPW) via pH-dependent extractions was performed to quantitatively investigate naphthenic acids (NAs, CnH2n+ZO2) and oxidized NAs (Ox-NAs) species (CnH2n+ZO3 and CnH2n+ZO4) using ultra-performance liquid chromatography time-of-flight mass spectrometry (UPLC-TOFMS). A mathematical model was also developed to estimate the dissociation constant pKa for NAs species, considering the liquid-liquid extraction process and the aqueous layer acid-base equilibrium. This model provides estimated dissociation constants for compounds in water samples based on fractionation extraction and relative quantification. Overall, the sum of O2-, O3-, and O4-NAs species accounted for 33.6% of total extracted organic matter. Accumulative extracted masses at different pHs revealed that every oxygen atom added to NAs increases the pKa (i.e., O2-NAs<O3-NAs<O4-NAs), indicating that the additional O atoms exist as -OH in O3- and O4-NAs. Molecule electron-withdrawing groups such as double bonds and aromatic groups, as indicated by higher carbon and -Z number, may be responsible for the lower pKa of O2-, O3-, and O4-NAs. The model obtained estimated pKa values of 3.5 for O2-NAs, 4.8 for O3-NAs, and 6.8 fo...Continue Reading

References

Nov 18, 2003·Analytical Chemistry·Dawen Kou, Somenath Mitra
Dec 21, 2004·Water Research·Yoshihiro KojimaKohichi Yagishita
Aug 5, 2008·Mass Spectrometry Reviews·John V HeadleyMark P Barrow
Dec 10, 2009·Proceedings of the National Academy of Sciences of the United States of America·Erin N KellyBarbra L Fortin
Sep 10, 2010·The Science of the Total Environment·David M GrewerPhillip M Fedorak
Sep 13, 2011·The Science of the Total Environment·Mohamed Gamal El-DinDaniel W Smith
Apr 24, 2013·Environmental Science & Technology·Alberto S PereiraJonathan W Martin
Jul 19, 2013·Environmental Science & Technology·Beili WangJianying Hu
Nov 21, 2013·Water Research·Charles E WestSteven J Rowland
Mar 5, 2014·Rapid Communications in Mass Spectrometry : RCM·Sabine K LenggerSteven J Rowland

❮ Previous
Next ❯

Citations

Apr 13, 2019·The Science of the Total Environment·Rongfu HuangMohamed Gamal El-Din
Jul 9, 2020·Environmental Science & Technology·Markus BrinkmannMarkus Hecker

❮ Previous
Next ❯

Related Concepts

Trending Feeds

COVID-19

Coronaviruses encompass a large family of viruses that cause the common cold as well as more serious diseases, such as the ongoing outbreak of coronavirus disease 2019 (COVID-19; formally known as 2019-nCoV). Coronaviruses can spread from animals to humans; symptoms include fever, cough, shortness of breath, and breathing difficulties; in more severe cases, infection can lead to death. This feed covers recent research on COVID-19.

Blastomycosis

Blastomycosis fungal infections spread through inhaling Blastomyces dermatitidis spores. Discover the latest research on blastomycosis fungal infections here.

Nuclear Pore Complex in ALS/FTD

Alterations in nucleocytoplasmic transport, controlled by the nuclear pore complex, may be involved in the pathomechanism underlying multiple neurodegenerative diseases including Amyotrophic Lateral Sclerosis and Frontotemporal Dementia. Here is the latest research on the nuclear pore complex in ALS and FTD.

Applications of Molecular Barcoding

The concept of molecular barcoding is that each original DNA or RNA molecule is attached to a unique sequence barcode. Sequence reads having different barcodes represent different original molecules, while sequence reads having the same barcode are results of PCR duplication from one original molecule. Discover the latest research on molecular barcoding here.

Chronic Fatigue Syndrome

Chronic fatigue syndrome is a disease characterized by unexplained disabling fatigue; the pathology of which is incompletely understood. Discover the latest research on chronic fatigue syndrome here.

Evolution of Pluripotency

Pluripotency refers to the ability of a cell to develop into three primary germ cell layers of the embryo. This feed focuses on the mechanisms that underlie the evolution of pluripotency. Here is the latest research.

Position Effect Variegation

Position Effect Variagation occurs when a gene is inactivated due to its positioning near heterochromatic regions within a chromosome. Discover the latest research on Position Effect Variagation here.

STING Receptor Agonists

Stimulator of IFN genes (STING) are a group of transmembrane proteins that are involved in the induction of type I interferon that is important in the innate immune response. The stimulation of STING has been an active area of research in the treatment of cancer and infectious diseases. Here is the latest research on STING receptor agonists.

Microbicide

Microbicides are products that can be applied to vaginal or rectal mucosal surfaces with the goal of preventing, or at least significantly reducing, the transmission of sexually transmitted infections. Here is the latest research on microbicides.