Frustrated Lewis pair-like reactions of nucleophilic palladium carbenes with B(C6F5)3

Chemical Communications : Chem Comm
Peng CuiVlad M Iluc

Abstract

The reactions of two nucleophilic palladium carbene complexes with the strong Lewis acid B(C6F5)3 afforded two zwitterionic products. One of them features a remote nucleophilic attack at the para-carbon of the supporting ligand, while the other indicates C-F activation of B(C6F5)3. Both behaviours are reminiscent of the reactivity of frustrated Lewis pairs due to the steric inaccessibility of the nucleophilic carbon center, but are unprecedented for transition metal carbene complexes. Furthermore, when those reactions are carried out in the presence of H2, products resulting from H2 splitting are observed.

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Citations

Oct 1, 2015·Dalton Transactions : an International Journal of Inorganic Chemistry·Thibault Cheisson, Audrey Auffrant
Jan 11, 2016·Chemistry : a European Journal·Julia WeismannViktoria H Gessner
Mar 24, 2016·Journal of the American Chemical Society·Nikola S LambicElon A Ison
Aug 26, 2015·Chemical Communications : Chem Comm·Julia Weismann, Viktoria H Gessner
Feb 3, 2016·Chemical Communications : Chem Comm·Cezar C Comanescu, Vlad M Iluc
Jul 29, 2016·Dalton Transactions : an International Journal of Inorganic Chemistry·Joel D SmithJavier Borau-Garcia
Mar 14, 2017·Dalton Transactions : an International Journal of Inorganic Chemistry·Lauren E DoyleDavid W Bi
Sep 5, 2017·Chemistry : a European Journal·Patrick E RothsteinVlad M Iluc
Mar 10, 2018·Chemistry : a European Journal·Niklas ZwettlerNadia C Mösch-Zanetti
Feb 2, 2019·Chemistry : a European Journal·Niklas Zwettler, Nadia C Mösch-Zanetti
Mar 21, 2019·Dalton Transactions : an International Journal of Inorganic Chemistry·Peng CuiVlad M Iluc
Sep 10, 2019·Chemistry : a European Journal·Xiong SunCongqing Zhu
Jan 18, 2020·Chemistry : a European Journal·Xiong SunCongqing Zhu
Jan 24, 2020·Chemistry : a European Journal·Nereida HidalgoJesús Campos
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Aug 1, 2015·Chemical Science·C C ComanescuV M Iluc
Dec 1, 2015·Chemical Science·Peng Cui, Vlad M Iluc
Apr 9, 2021·Journal of the American Chemical Society·Melissa R Hoffbauer, Vlad M Iluc
Jun 20, 2021·Angewandte Chemie·Qingyang WangRowan D Young
Oct 28, 2021·Chemistry : a European Journal·Kai-Stephan FeichtnerViktoria H Gessner

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