Functionalization of P4 through Direct P-C Bond Formation

Chemistry : a European Journal
Jaap E BorgerKoop Lammertsma

Abstract

Research on chlorine-free conversions of P4 into organophosphorus compounds (OPCs) has a long track record, but methods that allow desirable, direct P-C bond formations have only recently emerged. These include the use of metal organyls, carbenes, carboradicals, and photochemical approaches. The versatile product scope enables the preparation of both industrially relevant organophosphorus compounds, as well as a broad range of intriguing new compound classes. Herein we provide a concise overview of recent breakthroughs and outline the acquired fundamental insights to aid future developments.

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Citations

Feb 14, 2018·Science·Michael B Geeson, Christopher C Cummins
Oct 8, 2019·Chemistry : a European Journal·Jonas BresienAlexander Villinger
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Sep 18, 2021·Dalton Transactions : an International Journal of Inorganic Chemistry·Volker Jens EilrichEvamarie Hey-Hawkins

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Methods Mentioned

BETA
electron diffraction
NMR

Software Mentioned

SusPhos

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