Functionalization of polyoxometalates: towards advanced applications in catalysis and materials science

Chemical Communications : Chem Comm
Anna ProustPierre Gouzerh

Abstract

Functionalization via covalent grafting of organic functions allows to tune the redox and acid-base properties, and the solubility of polyoxometalates, to enhance their stability and biological activity and to reduce their toxicity, to facilitate their implementation in extended structures and functional devices. We discuss herein the electronic and binding connections, and the various synthesis methodologies. We emphasize on organonitrogen, organosilyl and organophosphonyl derivatives with special attention to synthesis, characterization and potential applications in catalysis and materials science. We also consider the giant molybdenum oxide-based clusters especially the porous capsule-type clusters (Keplerates) which have high relevance to this context.

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Citations

Nov 20, 2013·Chemical Reviews·Miao SunJean-Marie Basset
Oct 28, 2011·Inorganic Chemistry·Gregory AbsillisTatjana N Parac-Vogt
Oct 26, 2012·Inorganic Chemistry·Maria Barsukova-StuckartUlrich Kortz
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Dec 5, 2013·Inorganic Chemistry·Donghui YangJingyang Niu
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Jun 16, 2010·Chemical Communications : Chem Comm·Hai-jun PangZhong-min Su
Sep 11, 2010·Chemical Communications : Chem Comm·Jean-Daniel CompainPierre Mialane
Feb 11, 2011·Chemical Communications : Chem Comm·Xikui Fang, Marshall Luban
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Apr 21, 2017·Chemical Communications : Chem Comm·Grzegorz MarkiewiczPaolo Samorì

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