Further Investigations of the ClO Rotational Spectrum

Journal of Molecular Spectroscopy
Brian J. DrouinManfred Birk

Abstract

Pure rotational transitions of the chlorine monoxide radical have been observed up to v=2 in the X(1) (2)Pi(3/2) and X(2) (2)Pi(1/2) states and transitions of the (35)Cl(18)O isotopomer have been observed in natural abundance. Additionally, rotational transitions for levels up to J'=115/2 have been measured in the far infrared. These data have been merged with the existing microwave, submillimeter, and high-resolution infrared transition frequencies and fit simultaneously with a set of isotopically independent parameters. Isotopic substitution of both the Cl and O atoms has enabled the first determination of the electron spin-rotation constant gamma=-296.0(43) MHz as well as the Born-Oppenheimer corrections to the rotational constants. Copyright 2001 Academic Press.

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Citations

Jul 19, 2012·The Journal of Chemical Physics·Brian J DrouinHolger S P Müller
Oct 2, 2009·The Journal of Chemical Physics·Jetze SikkemaMiroslav Ilias
Nov 25, 2011·The Journal of Chemical Physics·E GershnabelI Sh Averbukh
Dec 3, 2008·The Journal of Chemical Physics·Toshiaki OkabayashiMitsutoshi Tanimoto
Jul 23, 2004·The Journal of Chemical Physics·Brian J DrouinCharles E Miller
Jan 22, 2018·The Journal of Chemical Physics·Junzi LiuLan Cheng
Apr 16, 2003·Chemistry : a European Journal·Rodion KopitzkyHelge Willner
Jul 20, 2011·Physical Chemistry Chemical Physics : PCCP·V BritesM Hochlaf
Jun 18, 2005·Physical Chemistry Chemical Physics : PCCP·Stephen A Cooke, Michael C L Gerry
Jul 22, 2017·Medical Oncology·Amana Saadallah-KallelRaja Mokdad-Gargouri
Mar 2, 2010·The Journal of Physical Chemistry. a·Daniel J GrantDavid A Dixon
Nov 3, 2006·The Journal of Physical Chemistry. a·Benjamin C Shepler, Kirk A Peterson
Dec 22, 2006·The Journal of Physical Chemistry. a·Kirk A PetersonHermann Stoll

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