GaCl3-assisted [2 + 3] cycloaddition: a route to tetrazaphospholes

Chemical Communications : Chem Comm
Alexander VillingerAxel Schulz

Abstract

The GaCl3-assisted [2 + 3] cycloaddition of Mes*-N=P-Cl (Mes* = 2,4,6-tBu3C6H2) with trimethylsilylazide (TMS-N3) results in the formation of the first tetrazaphosphole, stabilized as a GaCl3 adduct in high yields (>96%).

References

Nov 1, 2005·Angewandte Chemie·Sebastian HerlerJan J Weigand

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Citations

Jul 12, 2012·Inorganic Chemistry·Christian HeringAlexander Villinger
Apr 26, 2013·Inorganic Chemistry·Christian HeringAlexander Villinger
Jun 19, 2013·Inorganic Chemistry·Christian HeringAlexander Villinger
Jun 16, 2015·Dalton Transactions : an International Journal of Inorganic Chemistry·M H Holthausen, J J Weigand
Nov 28, 2018·Dalton Transactions : an International Journal of Inorganic Chemistry·Axel SchulzAlexander Villinger
May 8, 2010·Dalton Transactions : an International Journal of Inorganic Chemistry·René KuzoraRonald Wustrack
Oct 8, 2019·Chemistry : a European Journal·Jonas BresienAlexander Villinger
Jul 21, 2015·Angewandte Chemie·Christian Hering-Junghans, Eric Rivard
Apr 22, 2015·Angewandte Chemie·Jonas BresienAlexander Villinger
Feb 18, 2012·Chemistry : a European Journal·Axel Schulz, Alexander Villinger
May 18, 2021·Journal of the American Chemical Society·Martin-Louis Y RiuChristopher C Cummins

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