{Ge9[Si(SiMe3)3]2}(2-): a starting point for mixed substituted metalloid germanium clusters

Dalton Transactions : an International Journal of Inorganic Chemistry
Oleksandr Kysliak, A Schnepf

Abstract

Deeper investigations on the silylation reaction of the Ge9(4-) Zintl anion are provided. The reaction of K4Ge9 with two equivalents of ClHyp (Hyp = Si(SiMe3)3) gives the metalloid cluster compound [Ge9(Hyp)2](2-). Subsequent reactions with this compound give access to the first mixed trisubstituted metalloid cluster [Ge9(Hyp)2(Hyp(Ph3))](-) (Hyp(Ph3) = Si(SiMe3)2(SiPh3)), opening a way to a variety of mixed substituted Ge9 clusters for future investigations.

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Citations

Jul 30, 2017·Molecules : a Journal of Synthetic Chemistry and Natural Product Chemistry·Felix S GeitnerThomas F Fässler
Feb 22, 2018·Chemistry : a European Journal·Bastian WeinertStefanie Dehnen
Apr 21, 2018·Dalton Transactions : an International Journal of Inorganic Chemistry·Yannic Heider, David Scheschkewitz
May 15, 2018·Chemistry : a European Journal·Sabine FrischhutThomas F Fässler
Jul 13, 2018·Angewandte Chemie·Felix S GeitnerThomas F Fässler
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Jan 12, 2019·Angewandte Chemie·Kinga I LeszczyńskaDavid Scheschkewitz
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Feb 25, 2020·Angewandte Chemie·Nadine E PoitiersDavid Scheschkewitz
May 5, 2020·Dalton Transactions : an International Journal of Inorganic Chemistry·C WallachT F Fässler
Oct 17, 2017·Chemical Communications : Chem Comm·K MayerT F Fässler
Jul 28, 2019·Dalton Transactions : an International Journal of Inorganic Chemistry·Nadine C MichenfelderAndreas-Neil Unterreiner
Nov 1, 2016·Chemistry : a European Journal·Oleksandr KysliakAndreas Schnepf
Jul 12, 2019·Chemical Science·Nikolay V Tkachenko, Alexander I Boldyrev
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Oct 6, 2020·Inorganic Chemistry·Felix S Geitner, Thomas F Fässler
Feb 12, 2019·Inorganic Chemistry·Lorenz J SchiegerlThomas F Fässler

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