Ge(ii) cation catalyzed hydroboration of aldehydes and ketones

Dalton Transactions : an International Journal of Inorganic Chemistry
Soumen SinhababuSelvarajan Nagendran

Abstract

Well-defined germylene cations [(i-Bu)2ATI]GeOTf (4) and [(i-Bu)2ATIGe][GaCl4] (5) are isolated, and the catalytic utility of compound 4 for the hydroboration of a variety of aldehydes and ketones is reported (ATI = aminotroponiminate).

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Citations

Feb 16, 2021·Chemistry, an Asian Journal·Nilanjana Sen, Shabana Khan
Jun 26, 2021·Chemistry : a European Journal·Debotra SarkarShigeyoshi Inoue

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Methods Mentioned

BETA
NMR
X-ray

Software Mentioned

GAUSSIAN

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